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液液萃取-固相萃取富集地下水中毒杀芬的对比研究

饶竹, 谢原利, 陈巍

饶竹, 谢原利, 陈巍. 液液萃取-固相萃取富集地下水中毒杀芬的对比研究[J]. 岩矿测试, 2012, 31(4): 653-659.
引用本文: 饶竹, 谢原利, 陈巍. 液液萃取-固相萃取富集地下水中毒杀芬的对比研究[J]. 岩矿测试, 2012, 31(4): 653-659.
RAO Zhu, XIE Yuan-li, CHEN Wei. Comparison between Liquid-Liquid Extraction and Solid Phase Extraction for Toxaphene in Underground Water Samples[J]. Rock and Mineral Analysis, 2012, 31(4): 653-659.
Citation: RAO Zhu, XIE Yuan-li, CHEN Wei. Comparison between Liquid-Liquid Extraction and Solid Phase Extraction for Toxaphene in Underground Water Samples[J]. Rock and Mineral Analysis, 2012, 31(4): 653-659.

液液萃取-固相萃取富集地下水中毒杀芬的对比研究

基金项目: 

国土资源部公益性行业科研专项(200911043-28)

中国地质大调查项目(1212011120283, 1212010816028)

Comparison between Liquid-Liquid Extraction and Solid Phase Extraction for Toxaphene in Underground Water Samples

  • 摘要: 应用液液萃取、固相萃取柱、固相萃取盘等传统和现代富集技术,对半挥发性有机物进行提取,建立了气相色谱-负化学电离质谱测定地下水中毒杀芬的方法。对性能较好的自制GDX-502固相萃取柱进行了条件优化。结果表明,使用填制的GDX-502固相萃取柱富集地下水中的毒杀芬,基体加标回收率为92.3%~98.5%,优于商品固相苯取柱LC-C18、ENVITM-C18以及固相萃取盘(92.8%~96.8%)和液液萃取(80.3%~88.5%);GDX-502固相萃取柱富集速度低于固相萃取盘,但远高于LC-C18和ENVITM-C18;GDX-502固相萃取柱的批量处理样品能力(12个)高于固相萃取盘(6个);同时所使用的有机试剂量远低于液液萃取。GDX-502固相萃取柱的萃取效率、分析通量、经济性和环保性具有更大的优势。
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出版历程
  • 收稿日期:  2012-02-28

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