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元素分析仪-同位素比值质谱仪测定海洋沉积物有机碳稳定同位素方法初探

张媛媛, 贺行良, 孙书文, 朱志刚

张媛媛, 贺行良, 孙书文, 朱志刚. 元素分析仪-同位素比值质谱仪测定海洋沉积物有机碳稳定同位素方法初探[J]. 岩矿测试, 2012, 31(4): 627-631.
引用本文: 张媛媛, 贺行良, 孙书文, 朱志刚. 元素分析仪-同位素比值质谱仪测定海洋沉积物有机碳稳定同位素方法初探[J]. 岩矿测试, 2012, 31(4): 627-631.
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ZHANG Yuan-yuan, HE Xing-liang, SUN Shu-wen, ZHU Zhi-gang. A Preliminary Study on the Determination of Organic Carbon Stable Isotope of Marine Sediment by Element Analyzer-Isotope Ratio Mass Spectrometer[J]. Rock and Mineral Analysis, 2012, 31(4): 627-631.
Citation: ZHANG Yuan-yuan, HE Xing-liang, SUN Shu-wen, ZHU Zhi-gang. A Preliminary Study on the Determination of Organic Carbon Stable Isotope of Marine Sediment by Element Analyzer-Isotope Ratio Mass Spectrometer[J]. Rock and Mineral Analysis, 2012, 31(4): 627-631.
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元素分析仪-同位素比值质谱仪测定海洋沉积物有机碳稳定同位素方法初探

  • 1.

    国土资源部海洋油气资源与环境地质重点实验室, 山东 青岛 266071

  • 2.

    青岛海洋地质研究所, 山东 青岛 266071

  • 3.

    国土资源部海洋油气资源与环境地质重点实验室, 山东 青岛 266071

  • 4.

    青岛海洋地质研究所, 山东 青岛 266071

  • 5.

    中国海洋大学海洋化学理论与工程技术教育部重点实验室, 山东 青岛 266100

  • 6.

    国土资源部海洋油气资源与环境地质重点实验室, 山东 青岛 266071

  • 7.

    青岛海洋地质研究所, 山东 青岛 266071

基金项目: 

中国地质大调查项目(1212011120271)

A Preliminary Study on the Determination of Organic Carbon Stable Isotope of Marine Sediment by Element Analyzer-Isotope Ratio Mass Spectrometer

  • 1.

    Key Laboratory of Marine Hydrocarbon Resources and Environmental Geology, Ministry of Land and Resources, Qingdao 266071, China

  • 2.

    Qingdao Institute of Marine Geology, Qingdao 266071, China

  • 3.

    Key Laboratory of Marine Hydrocarbon Resources and Environmental Geology, Ministry of Land and Resources, Qingdao 266071, China

  • 4.

    Qingdao Institute of Marine Geology, Qingdao 266071, China

  • 5.

    Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China

  • 6.

    Key Laboratory of Marine Hydrocarbon Resources and Environmental Geology, Ministry of Land and Resources, Qingdao 266071, China

  • 7.

    Qingdao Institute of Marine Geology, Qingdao 266071, China

摘要

    摘要
  • 摘要: 初步建立了利用元素分析仪-同位素比值质谱仪(EA-IRMS)联用技术测定海洋沉积物中有机碳稳定同位素的方法。标定了标准工作参考气CO2(δ13CvsPDB为-32.053‰);验证了仪器的稳定性,标准偏差为0.009‰;当离子流强度范围为0.4~8.7 V时,总体线性为0.0337‰/V,小于仪器线性指标0.06‰/V的要求;同时测定了国家标准物质GBW 04408、国际标准物质Urea和海洋沉积物样品M01的精密度和准确度,标准偏差在0.04‰~0.13‰范围内;并在三家实验室进行了测量比对实验,标准偏差小于0.20‰,满足地质样品再现性0.5‰的要求。所选样品区域δ13Corg 范围为-25.29‰~-22.30‰,表明该海域总有机碳是陆源和海源两种来源的混合物。
    Abstract: Element Analyzer-Isotope Ratio Mass Spectrometer (EA-IRMS) technology was applied to determine organic carbon stable isotopes of marine sediment. Pure CO2 reference gas was calibrated via GBW 04408, and the δ13CvsPDB value of pure CO2 was determined to be -32.053‰. The stability and linearity of the EA-IRMS system were tested and verified through several experimental comparisons. The standard deviation of stability was 0.009‰. When ion intensities ranged from 0.4 to 8.7 V, the linearity of EA-IRMS system was 0.0337‰/V which was less than the requirement of linearity proxy of 0.06‰/V. Moreover, the precision and accuracy of the results for the national standard material of GBW 04408, international standard material of Urea and marine sediment sample of M01 were measured. The standard deviation was 0.13‰. The marine sediment samples were measured at three different labs. The standard deviation of the comparison results was less than 0.20‰ and met the need of reproducibility of 0.5‰. The TOC contents from marine sediment samples ranged from 0.13‰ to 1.11‰, with δ13Corg values ranging from -25.29‰ to -22.30‰, which indicate the derivation of organic matter from mixed terrestrial and marine organic materials.
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  • [4] Muzuka A N N, Shunula J P. Stable isotope compo-sitions of organic carbon and nitrogen of two mangrove stands along the Tanzanian coastal zone [J]. Estuarine, Coastal and Shelf Science,2006,52(12): 1625-1633.

    [4] Muzuka A N N, Shunula J P. Stable isotope compo-sitions of organic carbon and nitrogen of two mangrove stands along the Tanzanian coastal zone [J]. Estuarine, Coastal and Shelf Science,2006,52(12): 1625-1633.
    Dean W E, Arthur M A, Claypool G E. Depletion of 13C in Cretaceous marine organic matter: Source, diagenetic, or environmental signal? [J]. Marine Geology,1986,70(1-2): 119-157.

    Dean W E, Arthur M A, Claypool G E. Depletion of 13C in Cretaceous marine organic matter: Source, diagenetic, or environmental signal? [J]. Marine Geology,1986,70(1-2): 119-157.
    Philip A M, Elisabeth L V. Lacustrine sedimentary organic matter records of Late Quaternary paleoclimates [J]. Journal of Paleolimnology, 1999, 21(3): 345-372.

    Philip A M, Elisabeth L V. Lacustrine sedimentary organic matter records of Late Quaternary paleoclimates [J]. Journal of Paleolimnology, 1999, 21(3): 345-372.
    曾芳,毛治超.稳定碳同位素分析技术及其在地球化学中的应用[J].石油天然气学报:江汉石油学院学报, 2010, 32(2): 228-231.
    王万春,吉利明.有机碳和有机分子碳同位素的地球化学意义[J].地球科学进展,1997,12(5): 474-478.
    Ranjan R K, Routh J, Ramanathan A L, Klump J V. Elemental and stable isotope records of organic matter input and its fate in the Pichavaram mangrove-estuarine sediments [J]. Marine Chemistry,2011,126(1-4):163-172.

    Ranjan R K, Routh J, Ramanathan A L, Klump J V. Elemental and stable isotope records of organic matter input and its fate in the Pichavaram mangrove-estuarine sediments [J]. Marine Chemistry,2011,126(1-4):163-172.
    张恩楼,沈吉,夏威岚,朱育新,王苏民.青海湖沉积物有机碳及其同位素的气候环境信息[J].海洋地质与第四纪地质, 2002, 22(2): 105-108.
    薛博,严重玲,傅强.水体沉积物中有机碳和有机分子碳稳定同位素研究进展[J].海洋科学,2007,31(6): 87-97.
    王秋良,谢远云,梅惠.湖泊沉积物中有机碳同位素特征及其古气候环境意义[J].安全与环境工程, 2003, 10(4): 17-21.
    葛晨东,王颖, Pedersen T F, Laymaker O S.海南岛万泉河口沉积物有机碳、氮同位素的特征及其环境意义[J].第四纪研究, 2007, 59(7): 249-256.
    Boutton T W, Archer S R, Midwood A J. δ13C values of soil organic carbon and their use in documenting vegetation change in a subtropical savanna ecosystem [J].Geoderma,1998, 82(1-3): 5-41.

    Boutton T W, Archer S R, Midwood A J. δ13C values of soil organic carbon and their use in documenting vegetation change in a subtropical savanna ecosystem [J].Geoderma,1998, 82(1-3): 5-41.
    Galimov E M. Isotope organic geochemistry [J].Organic Geochemistry,2006,37(10): 1200-1262.

    Galimov E M. Isotope organic geochemistry [J].Organic Geochemistry,2006,37(10): 1200-1262.
    储雪蕾.一种新的快速的碳、氮、硫同位素测定手段——EA-IRMS连线分析技术[J].矿物岩石地球化学通报,1996,15(4): 259-262.
    马龙,吴敬禄.安固里淖湖积物中总有机碳含量及其碳同位素的环境意义[J].自然资源学报, 2009,24(6): 1009-1104.
    郑永飞,龚冰,王峥荣.岩石中碳同位素比值的EA-MS测定及其地球化学应用[J].地质论评,1999,45(5): 529-538.
    Grassineau N V. High-precision EA-IRMS analysis of S and C isotopes in geological materials[J]. Applied Geochemistry,2006,21(5): 756-765.

    Grassineau N V. High-precision EA-IRMS analysis of S and C isotopes in geological materials[J]. Applied Geochemistry,2006,21(5): 756-765.
    Rogers K M. Stable carbon and nitrogen isotope signa-tures indicate recovery of marine biota from sewage pollution at Moa Point, New Zealand [J].Marine Pollution Bulletin, 2003, 46(7): 821-827.

    Rogers K M. Stable carbon and nitrogen isotope signa-tures indicate recovery of marine biota from sewage pollution at Moa Point, New Zealand [J].Marine Pollution Bulletin, 2003, 46(7): 821-827.
    祁彪,丁玲玲,崔杰华,王颜红.EA-IRMS法测定不同类型土壤有机碳稳定性同位素组成[J].核农学报, 2009, 23(3): 492-496.
    崔杰华,祁彪,王颜红.植物样品中稳定碳同位素EA-IRMS系统分析方法[J].质谱学报, 2008, 29(1): 24-29.
    Jiang G Q, Wang X Q, Shi X Y, Xiao S H, Zhang S H, Dong J. The origin of decoupled carbonate and organic carbon isotope signatures in the early Cambrian (ca. 542-520 Ma) Yangtze platform[J]. Earth and Planetary Science Letters, 2012, 317-318: 96-110.

    Jiang G Q, Wang X Q, Shi X Y, Xiao S H, Zhang S H, Dong J. The origin of decoupled carbonate and organic carbon isotope signatures in the early Cambrian (ca. 542-520 Ma) Yangtze platform[J]. Earth and Planetary Science Letters, 2012, 317-318: 96-110.
    尹观,倪师军.同位素地球化学[M].北京:地质出版社, 2009: 285-288.
    Bird M I, Grocke D R. Determination of the abundance and carbon isotope composition of elemental carbon in sediment [J]. Geochimica et Cosmochimica, 1997, 61(16): 3413-3423.

    Bird M I, Grocke D R. Determination of the abundance and carbon isotope composition of elemental carbon in sediment [J]. Geochimica et Cosmochimica, 1997, 61(16): 3413-3423.
    王政,刘卫国,文启彬.土壤样品中氮同位素组成的元素分析仪-同位素质谱分析方法[J]. 质谱学报, 2005, 26(2): 71-75.
    Feurstein T P, Ostrom P H, Ostrom N E. Isotopic biogeochemoistry of dissolved organic nitrogen: A new technique and application [J]. Organic Geochemistry, 1997, 27(7-8): 363-370.

    Feurstein T P, Ostrom P H, Ostrom N E. Isotopic biogeochemoistry of dissolved organic nitrogen: A new technique and application [J]. Organic Geochemistry, 1997, 27(7-8): 363-370.
    丁悌平.稳定同位素测试技术与参考物质研究现状及发展趋势[J].岩矿测试,2002,21(4): 291-300.
    Jiang G Q, Wang X Q, Shi X Y, Zhang S H, Xiao S H, Dong J. Organic carbon isotope constraints on the dissolved organic carbon (DOC) reservoir at the Cryogenian-Ediacaran transition[J]. Earth and Planetary Science Letters,2010,299 (1-2): 159-168.

    Jiang G Q, Wang X Q, Shi X Y, Zhang S H, Xiao S H, Dong J. Organic carbon isotope constraints on the dissolved organic carbon (DOC) reservoir at the Cryogenian-Ediacaran transition[J]. Earth and Planetary Science Letters,2010,299 (1-2): 159-168.
    Williford K H, Ward P D, Garrison G H, Buick R. An extended organic carbon-isotope record across the Triassic-Jurassic boundary in the Queen Charlotte Islands, British Columbia, Canada[J]. Palaeo-geography, Palaeoclimatology, Palaeoecology,2007,244(1-4): 290-296.

    Williford K H, Ward P D, Garrison G H, Buick R. An extended organic carbon-isotope record across the Triassic-Jurassic boundary in the Queen Charlotte Islands, British Columbia, Canada[J]. Palaeo-geography, Palaeoclimatology, Palaeoecology,2007,244(1-4): 290-296.
    Müller A, Voss M. The palaeoenvironments of coastal lagoons in the southern Baltic Sea. Ⅱ. δ13C and δ15N ratios of organic matter-sources and sediments[J].Palaeogeography, Palaeoclimatology, Palaeoecology, 1999, 145(1-3): 17-32.

    Müller A, Voss M. The palaeoenvironments of coastal lagoons in the southern Baltic Sea. Ⅱ. δ13C and δ15N ratios of organic matter-sources and sediments[J].Palaeogeography, Palaeoclimatology, Palaeoecology, 1999, 145(1-3): 17-32.
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  • 收稿日期:  2011-12-07

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