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山东烟台地区苹果果园土壤中DDTs和HCHs残留分布特征与来源解析

史冰洁, 李小娜, 帅琴, 庞绪贵, 代杰瑞, 胡圣虹

史冰洁, 李小娜, 帅琴, 庞绪贵, 代杰瑞, 胡圣虹. 山东烟台地区苹果果园土壤中DDTs和HCHs残留分布特征与来源解析[J]. 岩矿测试, 2012, 31(2): 318-324.
引用本文: 史冰洁, 李小娜, 帅琴, 庞绪贵, 代杰瑞, 胡圣虹. 山东烟台地区苹果果园土壤中DDTs和HCHs残留分布特征与来源解析[J]. 岩矿测试, 2012, 31(2): 318-324.
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SHI Bing-jie, LI Xiao-na, SHUAI Qin, PANG Xu-gui, DAI Jie-rui, HU Sheng-hong. Distribution Characteristics and Source Apportionment of DDTs and HCHs in Soils from Apple Orchards in Yantai, Shandong Province[J]. Rock and Mineral Analysis, 2012, 31(2): 318-324.
Citation: SHI Bing-jie, LI Xiao-na, SHUAI Qin, PANG Xu-gui, DAI Jie-rui, HU Sheng-hong. Distribution Characteristics and Source Apportionment of DDTs and HCHs in Soils from Apple Orchards in Yantai, Shandong Province[J]. Rock and Mineral Analysis, 2012, 31(2): 318-324.
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山东烟台地区苹果果园土壤中DDTs和HCHs残留分布特征与来源解析

  • 1.

    生物地质与环境地质国家重点实验室, 中国地质大学(武汉), 湖北 武汉 430074

  • 2.

    中国地质大学(武汉)材料与化学学院, 湖北 武汉 430074

  • 3.

    中国地质大学(武汉)材料与化学学院, 湖北 武汉 430074

  • 4.

    山东省地质调查院, 山东 济南 250013

  • 5.

    山东省地质调查院, 山东 济南 250013

  • 6.

    生物地质与环境地质国家重点实验室, 中国地质大学(武汉), 湖北 武汉 430074

基金项目: 

山东省东部地区农业生态地球化学调查项目(鲁国土资字[2006]709号)

国家自然科学基金项目(40973021)

Distribution Characteristics and Source Apportionment of DDTs and HCHs in Soils from Apple Orchards in Yantai, Shandong Province

  • 1.

    State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences (Wuhan), Wuhan 430074, China

  • 2.

    Faculty of Material Science and Chemistry, China University of Geosciences (Wuhan), Wuhan 430074, China

  • 3.

    Faculty of Material Science and Chemistry, China University of Geosciences (Wuhan), Wuhan 430074, China

  • 4.

    Shandong Institute of Geological Survey, Jinan 250013, China

  • 5.

    Shandong Institute of Geological Survey, Jinan 250013, China

  • 6.

    State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences (Wuhan), Wuhan 430074, China

摘要

    摘要
  • 摘要: 为研究不同土壤类型中有机氯农药的残留特征、降解程度和来源途径,采集了山东烟台9个不同地质单元苹果园根系土壤和剖面土壤样品,用电子捕获检测器气相色谱法测定其中的滴滴涕(DDTs)和六六六(HCHs)。结果表明,研究区所有类型根系土壤中DDTs和HCHs均未超出《土壤环境质量标准》的二级土壤限值 (500 ng/g);土壤中DDTs的残留量及检出率均高于HCHs,DDTs检出率为100%,平均残留量为71.7 ng/g,而HCHs的检出率为19.70%,平均残留量为7.9 ng/g;根系土壤中DDTs各异构体平均浓度依次为p,p＇-DDT> p,p＇-DDE> o,p＇-DDT > p,p＇-DDD,而HCHs大部分以α-HCH形式存在,部分以β-HCH、γ-HCH存在。不同类型土壤中有机氯农药残留分布特征明显不同:DDTs在棕壤土(臧家庄)中最高(145.5 ng/g), 在中粗粒砂土(武宁)中最低(24.1 ng/g);而HCHs在细砂质壤土(蛇窝泊)中最高(27.9 ng/g)。各剖面土壤DDTs均在<20 cm层位中残留最高。DDTs和HCHs来源解析表明:研究区土壤为好氧条件;麻砂棕壤(官道和桃村)、黏细壤土(牟平)、细砂质壤土(蛇窝泊)和棕壤土(臧家庄)近年来仍有新的DDTs输入;大部分根系土壤均未发现HCHs新来源,但麻砂棕壤(桃村)在HCHs禁用后可能仍存在林丹的使用。
    Abstract: In order to study characteristics of residues, levels of degradation and sources of organochlorine pesticides (OCPs), Gas Chromatography-Electron Capture Detector (GC-ECD) was used to determine concentrations of DDTs and HCHs in 9 different types of root system soil and soil profiles from apple orchards in Yantai, Shangdong Province. None of the DDTs and HCHs in the soil samples exceeded the guidelines of 500 ng/g in the Chinese environmental quality standard for soils. The mean concentration of DDTs and HCHs were 71.7 ng/g and 7.9 ng/g, respectively. The detection rate of DDTs was 100%, while only 19.7% of soil samples contained HCHs. The mean levels of DDTs isomers hosted in the root system soil decreased in the following orders: p,p'-DDT> p,p'-DDE> o,p'-DDT > p,p'-DDD, while HCHs isomers were mainly α-HCH with minor β-HCH and γ-HCH. Distribution of OCPs varied in different types of soil: highest concentration of DDTs occurred in brunisolic soil (Zangjiazhuang, 145.5 ng/g) and lowest occurred in medium-grained sandy soil (Wuning, 24.1 ng/g). The highest concentration of HCHs occurred in fine sandy loam (Shewo, 27.9 ng/g). DDTs in soil profiles accumulated in depths within 20 cm. The results of source apportionment of DDTs and HCHs indicated all soil from the research area was aerobic. There were new sources of DDTs for linen sandy brunisolic soil (Guandao and Taocun), fine loam (Muping), fine sandy loam (Shewo) and brunisolic soil (Zangjiazhuang). No new sources of HCHs for most root system soil were apparent, but lindane may still have been used in linen sandy brunisolic soil (Taocun) after HCHs were restricted in China.
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    • 参考文献(21)
  • Gong Z M, Xu F L, Dawson R, Cao J, Liu W X, Li B G, Shen W R, Zhang W J, Qin B P, Sun R, Tao S. Residues of hexachlorocyclohexane isomers and their distribution characteristics in soils in the Tianjin area, China [J]. Archives of Environmental Contamination and Toxicology, 2004, 46: 432-437.

    Gong Z M, Xu F L, Dawson R, Cao J, Liu W X, Li B G, Shen W R, Zhang W J, Qin B P, Sun R, Tao S. Residues of hexachlorocyclohexane isomers and their distribution characteristics in soils in the Tianjin area, China [J]. Archives of Environmental Contamination and Toxicology, 2004, 46: 432-437.
    Vijgen J, Abhilash P C, Li Y F, Lal R, Forter M, Torres J, Singh N, Yunus M, Tian C G, Schäffer A, Weber R. Hexachlorocyclohexane (HCH) as new stockholm convention POPs—A global perspective on the management of lindane and its waste isomers [J]. Environmental Science and Pollution Research, 2011, 18: 152-162.

    Vijgen J, Abhilash P C, Li Y F, Lal R, Forter M, Torres J, Singh N, Yunus M, Tian C G, Schäffer A, Weber R. Hexachlorocyclohexane (HCH) as new stockholm convention POPs—A global perspective on the management of lindane and its waste isomers [J]. Environmental Science and Pollution Research, 2011, 18: 152-162.
    Hermanson M H, Moss D J, Monosmith C L, Keeler G J. Spatial and temporal trends of gas and particle phase atmospheric DDT and metabolites in Michigan: Evidence of long-term persistence and atmospheric emission in a high-DDT-use fruit orchard [J]. Journal of Geophysical Research, 2007, 112:D04301.

    Hermanson M H, Moss D J, Monosmith C L, Keeler G J. Spatial and temporal trends of gas and particle phase atmospheric DDT and metabolites in Michigan: Evidence of long-term persistence and atmospheric emission in a high-DDT-use fruit orchard [J]. Journal of Geophysical Research, 2007, 112:D04301.
    Galiulin R V, Bashkin V N, Galiulin R A. Review: Behavior of persistent organic pollutants in the air-plant-soil system [J]. Water, Air, and Soil Pollution, 2002, 137: 179-191.

    Galiulin R V, Bashkin V N, Galiulin R A. Review: Behavior of persistent organic pollutants in the air-plant-soil system [J]. Water, Air, and Soil Pollution, 2002, 137: 179-191.
    Ruus A, Green N W, Maage A, Amundsen C E, Schøyen M, Skei J. Post World War Ⅱ orcharding creates present day DDT—Problems in the Sørfjord (Western Norway)—A case study [J]. Marine Pollution Bulletin, 2010, 60: 1856-1861.

    Ruus A, Green N W, Maage A, Amundsen C E, Schøyen M, Skei J. Post World War Ⅱ orcharding creates present day DDT—Problems in the Sørfjord (Western Norway)—A case study [J]. Marine Pollution Bulletin, 2010, 60: 1856-1861.
    Zhang A P, Liu W P, Yuan H J, Zhou S S, Su Y S, Li Y F. Spatial distribution of hexachlorocyclohexanes in agricult-ural soils in Zhejiang Province, China, and correlations with elevation and temperature [J]. Environmental Science & Technology, 2011, 45: 6303-6308.

    Zhang A P, Liu W P, Yuan H J, Zhou S S, Su Y S, Li Y F. Spatial distribution of hexachlorocyclohexanes in agricult-ural soils in Zhejiang Province, China, and correlations with elevation and temperature [J]. Environmental Science & Technology, 2011, 45: 6303-6308.
    Hu W Y, Lu Y L, Wang T Y, Luo W, Zhang X, Geng J, Wang G, Shi Y J, Jiao W T, Chen C L. Factors affecting HCH and DDT in soils around watersheds of Beijing reservoirs, China [J]. Environmental Geo-chemistry and Health, 2010, 32(2): 85-94.

    Hu W Y, Lu Y L, Wang T Y, Luo W, Zhang X, Geng J, Wang G, Shi Y J, Jiao W T, Chen C L. Factors affecting HCH and DDT in soils around watersheds of Beijing reservoirs, China [J]. Environmental Geo-chemistry and Health, 2010, 32(2): 85-94.
    Li J, Zhang G, Qi S H, Li X D, Peng X Z. Con-centrations, enantiomeric compositions, and sources of HCH, DDT and chlordane in soils from the Pearl River Delta, South China [J]. Science of the Total Environment, 2006, 372(1): 215-224.

    Li J, Zhang G, Qi S H, Li X D, Peng X Z. Con-centrations, enantiomeric compositions, and sources of HCH, DDT and chlordane in soils from the Pearl River Delta, South China [J]. Science of the Total Environment, 2006, 372(1): 215-224.
    程翠莉.大连地区大气中DDT和HCH的监测与来源解析.大连:大连海事大学,2009: 20: 66-67.
    胡庆永.山东省烟台地区有机氯农药污染状况调查研究[J].山东农业大学学报:自然科学版,1981(2): 59-72.
    冯建国,陶训,张安盛,于毅.苹果园农药和重金属污染及其治理对策[J].中国农学通报,1998(3): 33-35.
    周晓燕,崔兆杰.土壤及果树中HCH和DDT残留及分布规律研究[J].环境科学与技术,2009(5): 62-65.
    杨世琦,刘国强,张爱平,王永生,杨正礼.北方典型区域果园表层土壤农药类POPs残留特征分析[J].农业环境科学学报,2010,29(8): 1515-1519.
    赵炳梓,张佳宝,周凌云,朱安宁,夏敏,卢信.黄淮海地区典型农业土壤中六六六(HCH)和滴滴涕(DDT)的残留量研究:Ⅰ.表层残留量及其异构体组成[J].土壤学报,2005,42(5):761-768.
    Boul H L, Garnham M L, Hucker D, Balrd D, Aislable J. Influence of agricultural practices on the levels of DDT and its residues in soil [J]. Environmental Science & Technology,1994,28(8): 1397-1402.

    Boul H L, Garnham M L, Hucker D, Balrd D, Aislable J. Influence of agricultural practices on the levels of DDT and its residues in soil [J]. Environmental Science & Technology,1994,28(8): 1397-1402.
    章海波,骆永明,赵其国,张甘霖,黄铭洪.香港土壤研究 Ⅳ.土壤中有机氯化合物的含量和组成[J].土壤学报,2006,43(2): 220-225.
    Manz M M,Wenzel K D,Dietze U,Schuurmann G. Persistent organic pollutants in agricultural soils of Central Germany [J]. Science of the Total Environment,2001,277(1-3): 187-198.

    Manz M M,Wenzel K D,Dietze U,Schuurmann G. Persistent organic pollutants in agricultural soils of Central Germany [J]. Science of the Total Environment,2001,277(1-3): 187-198.
    Gao H J, Jiang X, Wang F, Bian Y R, Wang D Z, Dend J C, Yan D Y. Residual levels and new inputs of chlorinated POPs in agricultural soils from Taihu Lake region [J]. Pedosphere,2005,15(3): 301-309.

    Gao H J, Jiang X, Wang F, Bian Y R, Wang D Z, Dend J C, Yan D Y. Residual levels and new inputs of chlorinated POPs in agricultural soils from Taihu Lake region [J]. Pedosphere,2005,15(3): 301-309.
    郝蓉,宋艳暾,万洪富,彭少麟.南亚热带典型地区农业土壤中多环芳烃和有机氯农药研究[J].生态学报,2007,27(5): 2021-2029.
    Covaci A, Hura C, Schepens P. Selected persistent organochlorine pollutants in Romania [J]. Science of the Total Environment,2001,280(1-3): 143-152.

    Covaci A, Hura C, Schepens P. Selected persistent organochlorine pollutants in Romania [J]. Science of the Total Environment,2001,280(1-3): 143-152.
    Murayama H, Takase Y, Mitobe H, Mukai H, Ohzeki T, Shimizu K, Kitayama Y. Seasonal change of persistent organic pollutant concentrations in air at Niigata area, Japan [J]. Chemosphere,2003,52(4): 683-694.

    Murayama H, Takase Y, Mitobe H, Mukai H, Ohzeki T, Shimizu K, Kitayama Y. Seasonal change of persistent organic pollutant concentrations in air at Niigata area, Japan [J]. Chemosphere,2003,52(4): 683-694.
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  • 收稿日期:  2011-09-13

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