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玄武岩标准样品铁铜锌同位素组成

唐索寒, 闫斌, 朱祥坤, 李津, 李世珍

唐索寒, 闫斌, 朱祥坤, 李津, 李世珍. 玄武岩标准样品铁铜锌同位素组成[J]. 岩矿测试, 2012, 31(2): 218-224.
引用本文: 唐索寒, 闫斌, 朱祥坤, 李津, 李世珍. 玄武岩标准样品铁铜锌同位素组成[J]. 岩矿测试, 2012, 31(2): 218-224.
TANG Suo-han, YAN Bin, ZHU Xiang-Kun, LI Jin, LI Shi-zhen. Iron, Copper and Zinc Isotopic Compositions of Basaltic Standard Reference Materials[J]. Rock and Mineral Analysis, 2012, 31(2): 218-224.
Citation: TANG Suo-han, YAN Bin, ZHU Xiang-Kun, LI Jin, LI Shi-zhen. Iron, Copper and Zinc Isotopic Compositions of Basaltic Standard Reference Materials[J]. Rock and Mineral Analysis, 2012, 31(2): 218-224.

玄武岩标准样品铁铜锌同位素组成

基金项目: 

中国地质大调查项目(1212011120295)

国土资源公益性行业科研专项经费项目(200911043-17)

Iron, Copper and Zinc Isotopic Compositions of Basaltic Standard Reference Materials

  • 摘要: 报道了三种玄武岩标准样品(BCR-2、BIR-1a和GBW 07105)的铁铜锌同位素数据。实验使用HNO3-HF混合酸消解玄武岩标准样品;AGMP-1阴离子交换树脂分离提纯样品中的铜铁锌,利用多接收等离子体质谱仪(MC-ICPMS)测定铁铜锌同位素比值,分析过程中使用样品-标准-样品交叉法校正仪器的质量分馏。实验得到BCR-2、BIR-1a和GBW 07105标准样品的高精度铁铜锌同位素组成(95%置信水平的不确定度)分别为:δ56FeBCR-2-IRMM014=0.070‰±0.018‰(2SD),δ65CuBCR-2-SRM976=0.16‰±0.04‰(2SD),δ66ZnBCR-2-IRMM3702=-0.072‰±0.020‰(2SD);δ56FeBIR-1a-IRMM014=0.044‰±0.026‰(2SD),δ65CuBIR-1a-SRM976=0.027‰±0.019‰(2SD),δ66ZnBIR-1a-IRMM3702=0.085‰±0.032‰(2SD);δ56FeGBW 07105-IRMM014=0.126‰±0.039‰(2SD),δ65CuGBW 07105-SRM976=0.12‰±0.01‰(2SD),δ66ZnGBW 07105-IRMM3702=0.22‰±0.03‰(2SD)。这些数据在误差(不确定度)范围内与国际上已发表的数据是一致的。三个玄武岩标准样品的铁铜锌同位素组成数据的发表为铁铜锌同位素研究提供了统一的标准,使地质样品的铁铜锌同位素数据的质量监控成为可能。
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  • 收稿日期:  2011-12-08

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