• 中文核心期刊
  • 中国科技核心期刊
  • CSCD来源期刊
  • DOAJ 收录
  • Scopus 收录
高级搜索

电感耦合等离子体质谱法测定硫时不同形态硫的影响

黄志丁, 王军, 逯海, 杨晓进

黄志丁, 王军, 逯海, 杨晓进. 电感耦合等离子体质谱法测定硫时不同形态硫的影响[J]. 岩矿测试, 2012, 31(1): 77-82.
引用本文: 黄志丁, 王军, 逯海, 杨晓进. 电感耦合等离子体质谱法测定硫时不同形态硫的影响[J]. 岩矿测试, 2012, 31(1): 77-82.
shu
HUANG Zhi-ding, WANG Jun, LU Hai, YANG Xiao-jin. The Effect on Sulfur Species during Determination of Sulfur by Inductively Coupled Plasma-Mass Spectrometry[J]. Rock and Mineral Analysis, 2012, 31(1): 77-82.
Citation: HUANG Zhi-ding, WANG Jun, LU Hai, YANG Xiao-jin. The Effect on Sulfur Species during Determination of Sulfur by Inductively Coupled Plasma-Mass Spectrometry[J]. Rock and Mineral Analysis, 2012, 31(1): 77-82.
shu

电感耦合等离子体质谱法测定硫时不同形态硫的影响

  • 1.

    北京化工大学化学工程学院, 北京 100029

  • 2.

    中国计量科学研究院, 北京 100013

  • 3.

    中国计量科学研究院, 北京 100013

  • 4.

    北京化工大学化学工程学院, 北京 100029

基金项目: 

2009年度质检公益性行业科研专项(200910105)

国家自然科学基金项目(20975008)

The Effect on Sulfur Species during Determination of Sulfur by Inductively Coupled Plasma-Mass Spectrometry

  • 1.

    College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China

  • 2.

    National Institute of Metrology, Beijing 100013, China

  • 3.

    National Institute of Metrology, Beijing 100013, China

  • 4.

    College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China

摘要

    摘要
  • 摘要: 电感耦合等离子体质谱(ICP-MS)常常被应用于矿石、蛋白质和化石燃料等材料中硫含量的测定。文章综合研究比较了四极杆电感耦合等离子体质谱(Q-ICP-MS)和扇形磁场电感耦合等离子体质谱(SF-ICP-MS)测定硫的灵敏度、检出限及空白干扰。重点考察了两种不同的样品介质(水和2% HNO3)中不同形态的硫对SF-ICP-MS测定硫信号的影响,并且深入研究了影响的原因。结果表明,硫含量相同但形态不同的含硫阴离子(S2-、S2O32-、SO32-、SO42-)在2%的HNO3介质中的信号比在水介质中的信号稳定,2%的HNO3更适合于作为ICP-MS测定硫的介质。在2%的HNO3介质中,S2-、SO32-中S的ICP-MS测量灵敏度(即标准曲线的斜率)分别为7828 cps/(μg·L-1)、5528 cps/(μg·L-1),SO42-和S2O32-的测量灵敏度分别是为1321 cps/(μg·L-1)、1299 cps/(μg·L-1)。S2-和SO32-的灵敏度分别约为SO42-的6倍和4倍;而S2O32-的灵敏度与SO42-基本一致。主要原因在于S2-、SO32-形态的硫在HNO3介质中形成了气态的H2S和SO2,相当于提高了雾化效率,从而使这两种形态硫的灵敏度大幅度提高。
    Abstract: Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) is often applied to determine sulfur in minerals, proteins, fossil fuels and other materials. The study of sensitivity, limit of detection and background noise during determination of sulfur, using both Quadrupole Inductively Coupled Plasma-Mass Spectrometry (Q-ICP-MS) and Sector Field Inductively Coupled Plasma-Mass Spectrometry (SF-ICP-MS), are presented in this paper. One focus of the paper is to study the effect on sulfur species during determination of sulfur in two different matrices (water and 2% HNO3) by SF-ICP-MS. The results indicate that the signals for S2-, S2O32-, SO32-, SO42-, respectively, in 2% HNO3 are consistently more stable than in water matrix. Therefore, the matrix of 2% HNO3 is more suitable for sulfur determination by ICP-MS. In addition, sulfur sensitivities for S2- were higher than those for SO42- and S2O32- by ICP-MS. The sulfur sensitivities of S2- and SO32- were 6 and 4 times higher respectively than those of S2O32- and SO42-. The reason for higher sulfur sensitivities for both S2- and SO32- is that the formation of aerosols (H2S and SO2) in 2% HNO3 improves atomization efficiency.
    • HTML全文
    • 参考文献(28)
  • Casella I G, Contursi M, Desimoni E.Amperometric detection of sulfur-containing compounds in alkaline media[J]. Analyst,2002,127(5): 647-652.

    Casella I G, Contursi M, Desimoni E.Amperometric detection of sulfur-containing compounds in alkaline media[J]. Analyst,2002,127(5): 647-652.
    Hassan S S M, Hamza M S A, Mohamed A H K. A novel spectrophotometric method for batch and flow injection determination of sulfite in beverages[J]. Analytica Chimica Acta,2006,570(2): 232-239.

    Hassan S S M, Hamza M S A, Mohamed A H K. A novel spectrophotometric method for batch and flow injection determination of sulfite in beverages[J]. Analytica Chimica Acta,2006,570(2): 232-239.
    孙登明,阮大文,王丽红.萃取催化光度法间接测定水中痕量硫离子[J].分析化学,2004,32(2): 179-182.
    肖晓辉.铅电解原料工业硅氟酸中硫酸根的快速测定[J].岩矿测试,2007,26(5): 421-422.
    黄兰芳,汪炳武.硫化物的快速分光光度法测定[J].分析化学,1997,25(10): 1192-1194.
    李忠,刘思远,黄海涛,王岚,施红林.烟草制品中硫含量测定的研究[J].光谱实验室,2000,17(5): 534-535.
    Steudler P A, Kijowski W. Determination of reduced sulfur gases in air by solid adsorbent preconcentration and gas chromatography[J]. Analytical Chemistry,1984,56:1432-1436.

    Steudler P A, Kijowski W. Determination of reduced sulfur gases in air by solid adsorbent preconcentration and gas chromatography[J]. Analytical Chemistry,1984,56:1432-1436.
    Yoo M, Lee S, Seog H, Shin D. Validation of high performance liquid chromatography methods for determination of bioactive sulfur compounds in garlic bulbs[J]. Food Science and Biotechnology,2010,19(6): 1619-1626.

    Yoo M, Lee S, Seog H, Shin D. Validation of high performance liquid chromatography methods for determination of bioactive sulfur compounds in garlic bulbs[J]. Food Science and Biotechnology,2010,19(6): 1619-1626.
    刘肖,滕曼,蔡亚岐,牟世芬.离子色谱法测定五氧化二铌和五氧化二钽中痕量氟氯和硫酸根离子的前处理方法[J].岩矿测试,2006,25(4): 319-322.
    Steinmeyer S, Kolbesen B. Capability and limitations of the determination of sulfur in inorganic and biological matrices by total reflection X-ray fluorescence spectrometry[J]. Spectrochimica Acta Part B: Atomic Spectroscopy,2001,56(11): 2165-2173.

    Steinmeyer S, Kolbesen B. Capability and limitations of the determination of sulfur in inorganic and biological matrices by total reflection X-ray fluorescence spectrometry[J]. Spectrochimica Acta Part B: Atomic Spectroscopy,2001,56(11): 2165-2173.
    刘玉纯,梁述廷,徐厚玲,吴永斌.X射线荧光光谱法测定生物样品中氯硫氮磷钾铜锌溴[J].岩矿测试,2008,27(1): 41-44.
    应晓浒,应林初.X射线荧光光谱测定灯用煤油中的微量硫[J].石油与天然气化工,2000,29(2): 94-95.
    李国会,马光祖,罗立强,吉昂,王庆广.X射线荧光光谱分析中不同价态硫对测定硫的影响及地质试样中全硫的测定[J].岩矿测试,1994,13(4): 294-298.
    Makishima A, Nakamura E. Determination of total sulfur at microgram per gram levels in geological materials by oxidation of sulfur into sulfate with in situ generation of bromine using isotope dilution high resolution ICPMS[J]. Analytical Chemistry,2001,73(11): 2547-2553.

    Makishima A, Nakamura E. Determination of total sulfur at microgram per gram levels in geological materials by oxidation of sulfur into sulfate with in situ generation of bromine using isotope dilution high resolution ICPMS[J]. Analytical Chemistry,2001,73(11): 2547-2553.
    Bouyssiere B, Leonhard P, Präfrock D, Baco F, Garcia C L, Wilbur S, Prange A .Investigation of the sulfur speciation in petroleum products by capillary gas chromatography with ICP collision cell-MS detection[J]. Journal of Analytical Atomic Spectrometry,2004,19: 700-702.

    Bouyssiere B, Leonhard P, Präfrock D, Baco F, Garcia C L, Wilbur S, Prange A .Investigation of the sulfur speciation in petroleum products by capillary gas chromatography with ICP collision cell-MS detection[J]. Journal of Analytical Atomic Spectrometry,2004,19: 700-702.
    Balkhi S E, Poupon J, Trocello J M, Massicot F, Woimant F, Laprévote O. Human plasma copper proteins speciation by size exclusion chromatography coupled to inductively coupled plasma mass spectrometry[J]. Analytical Chemistry,2010,82(16): 6904-6910.

    Balkhi S E, Poupon J, Trocello J M, Massicot F, Woimant F, Laprévote O. Human plasma copper proteins speciation by size exclusion chromatography coupled to inductively coupled plasma mass spectrometry[J]. Analytical Chemistry,2010,82(16): 6904-6910.
    王萌,丰伟悦,陆文伟,李柏,汪冰,朱墨桃,王云,赵宇亮,柴之芳.电感耦合等离子质谱间接法测定蛋白质含量[J].分析化学,2008,36(3): 321-324.
    Santamaria-Fernandez R, Hearn R,Wolff J C.Detection of counterfeit tablets of an antiviral drug using δ34S measurements by MC-ICP-MS and confirmation by LA-MC-ICP-MS and HPLC-MC-ICP-MS[J]. Journal of Analytical Atomic Spectrometry,2008,23(9): 1294-1299.

    Santamaria-Fernandez R, Hearn R,Wolff J C.Detection of counterfeit tablets of an antiviral drug using δ34S measurements by MC-ICP-MS and confirmation by LA-MC-ICP-MS and HPLC-MC-ICP-MS[J]. Journal of Analytical Atomic Spectrometry,2008,23(9): 1294-1299.
    Schaumläffel D, Giusti P, Preud'Homme H, Szpunar J, Lobiski R. Precolumn isotope dilution analysis in nanoHPLC-ICPMS for absolute quantification of sulfur-containing peptides[J]. Analytical Chemistry,2007,79(7): 2859-2868.

    Schaumläffel D, Giusti P, Preud'Homme H, Szpunar J, Lobiski R. Precolumn isotope dilution analysis in nanoHPLC-ICPMS for absolute quantification of sulfur-containing peptides[J]. Analytical Chemistry,2007,79(7): 2859-2868.
    Wang M, Feng W, Lu W, Li B, Wang B, Zhu M, Wang Y, Yuan H, Zhao Y, Chai Z. Quantitative analysis of proteins via sulfur determination by HPLC coupled to isotope dilution ICPMS with a hexapole collision cell [J]. Analytical Chemistry,2007,79(23): 9128-9134.

    Wang M, Feng W, Lu W, Li B, Wang B, Zhu M, Wang Y, Yuan H, Zhao Y, Chai Z. Quantitative analysis of proteins via sulfur determination by HPLC coupled to isotope dilution ICPMS with a hexapole collision cell [J]. Analytical Chemistry,2007,79(23): 9128-9134.
    Martinez-Sierra J G, Sanz F M, Espilez P H, Gayon J M M, Alonso J I G. Biosynthesis of sulfur-34 labelled yeast and its characterisation by multicollector-ICP-MS[J]. Journal of Analytical Atomic Spectrometry,2007,22(9): 1105-1112.

    Martinez-Sierra J G, Sanz F M, Espilez P H, Gayon J M M, Alonso J I G. Biosynthesis of sulfur-34 labelled yeast and its characterisation by multicollector-ICP-MS[J]. Journal of Analytical Atomic Spectrometry,2007,22(9): 1105-1112.
    何红蓼,杜安道,邹晓秋,孙亚莉,殷宁万.铼-锇测年法中锇的化学行为的研究[J].分析化学,1994,22(2): 109-114.
    李冰,何红蓼,史世云,马新荣,温宏利,吕彩芬.电感耦合等离子体质谱法同时测定地质样品中痕量碘溴硒砷的研究[J].岩矿测试,2001,20(3):161-166.
    郑聪,王金花,高峰,付光亮,冯骞.电感耦合等离子体-质谱法测定食用藻类植物中碘含量[J].食品科学,2011,32(8):202-205.
    Narukawa T, Kuroiwa T, Chiba K. Mechanism of sen-sitivity difference between trivalent inorganic As species and pentavalent species with inductively coupled plasma spectrometry [J]. Talanta,2007,73(1):157-165.

    Narukawa T, Kuroiwa T, Chiba K. Mechanism of sen-sitivity difference between trivalent inorganic As species and pentavalent species with inductively coupled plasma spectrometry [J]. Talanta,2007,73(1):157-165.
    Heilmann J, Heumann K G. Development of a species-unspecific isotope dilution GC-ICPMS method for possible routine quantification of sulfur species in petroleum products[J]. Analytical Chemistry,2008,80(6):1952-1961.

    Heilmann J, Heumann K G. Development of a species-unspecific isotope dilution GC-ICPMS method for possible routine quantification of sulfur species in petroleum products[J]. Analytical Chemistry,2008,80(6):1952-1961.
    Martinez-Sierra J G, Sanz F M, Espilez P H, Santamaria- Fernandez R, Gayon J M M, Alonso J I G.Evaluation of different analytical strategies for the quantification of sulfur-containing biomolecules by HPLC-ICP-MS:Application to the characterisation of 34S-labelled yeast [J]. Journal of Analytical Atomic Spectrometry,2010,25(7):989-997.

    Martinez-Sierra J G, Sanz F M, Espilez P H, Santamaria- Fernandez R, Gayon J M M, Alonso J I G.Evaluation of different analytical strategies for the quantification of sulfur-containing biomolecules by HPLC-ICP-MS:Application to the characterisation of 34S-labelled yeast [J]. Journal of Analytical Atomic Spectrometry,2010,25(7):989-997.
    Divjak B, Goessler W. Ion chromatographic separation of sulfur-containing inorganic anions with an ICP-MS as element-specific detector[J].Journal of Chromato-graphy A,1999,844(1-2):161-169.

    Divjak B, Goessler W. Ion chromatographic separation of sulfur-containing inorganic anions with an ICP-MS as element-specific detector[J].Journal of Chromato-graphy A,1999,844(1-2):161-169.
    • 相关文章
    • 施引文献
    • 资源附件(0)
计量
  • 文章访问数:  1669
  • HTML全文浏览量:  2
  • PDF下载量:  1297
  • 被引次数: 0
出版历程
  • 收稿日期:  2011-11-07

目录

摘要
HTML全文
    参考文献(28)
    相关文章
    施引文献
    资源附件(0)

    /

    返回文章
    返回

    主管单位：中国科学技术协会 主办单位：中国地质学会；国家地质实验测试中心

    通讯地址：北京市西城区百万庄大街26号 工作邮箱：ykcs_zazhi@163.com 办公电话：010-68999562

    京公网安备 11010202008159号 京ICP备2022024991号

    本系统由 北京仁和汇智信息技术有限公司 开发  百度统计