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废旧电容器封存点土壤中多氯联苯的残留特征

郑群雄, 徐小强, 马军, 曹攽, 刘清辉, 郑存江

郑群雄, 徐小强, 马军, 曹攽, 刘清辉, 郑存江. 废旧电容器封存点土壤中多氯联苯的残留特征[J]. 岩矿测试, 2011, 30(6): 699-704.
引用本文: 郑群雄, 徐小强, 马军, 曹攽, 刘清辉, 郑存江. 废旧电容器封存点土壤中多氯联苯的残留特征[J]. 岩矿测试, 2011, 30(6): 699-704.
ZHENG Qun-xiong, XU Xiao-qiang, MA Jun, CAO Ban, LIU Qing-hui, ZHENG Cun-jiang. Residue Characteristics of Polychlorinated Biphenyls in Soils from a Storage Site of Used Capacitors[J]. Rock and Mineral Analysis, 2011, 30(6): 699-704.
Citation: ZHENG Qun-xiong, XU Xiao-qiang, MA Jun, CAO Ban, LIU Qing-hui, ZHENG Cun-jiang. Residue Characteristics of Polychlorinated Biphenyls in Soils from a Storage Site of Used Capacitors[J]. Rock and Mineral Analysis, 2011, 30(6): 699-704.

废旧电容器封存点土壤中多氯联苯的残留特征

Residue Characteristics of Polychlorinated Biphenyls in Soils from a Storage Site of Used Capacitors

  • 摘要: 利用气相色谱-质谱联用法(GC-MS)研究了长江三角洲某废旧电容器封存点土壤中多氯联苯(PCBs)的残留特征。利用GC-MS的选择离子监测模式(SIM)对包括7种指示性PCBs和12种类二噁英PCBs共19种PCBs进行分析。统计结果显示,该封存点土壤中19种PCBs含量为2.01~5201.20 ng/g,平均含量为229.38 ng/g,明显高于国内一般土壤,但低于国内某些封存点土壤。土壤中19种PCBs同系物以低氯代(3~5氯)为主,三者占同系物总量的85.43%,尤以三氯代-PCB 28、四氯代-PCB 52和五氯代-PCB 118残留量最高。通过对比分析得出,封存点土壤PCBs以Aroclor 1242、Aroclor 1248为主,并含少量的Aroclor 1254。封存点土壤中PCBs残留量虽未超过控制值,但已呈现污染迹象,应及时采取控制措施,阻止污染趋势进一步扩大。
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  • 收稿日期:  2011-03-19

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