王水溶样-电感耦合等离子体发射光谱法同时测定铁铜铅锌硫化物矿石中8个元素
Simultaneous Determination of 8 Elemental Components of Fe, Cu, Zn and Pb in Sulfide Ores by ICP-AES with Aqua Regia Digestion
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摘要: 建立了王水溶样-电感耦合等离子体发射光谱法同时测定铁、铜、铅、锌硫化物矿中Cu、Pb、Zn、As、Ag、Cd、Hg和Mo等8个元素的分析方法。确定了方法的溶矿及测定条件,用国家一级标准物质GBW07162(多金属贫矿石)和GBW07164(多金属矿石)进行精密度实验,除个别元素外,大多数的元素精密度(RSD,n＝11)小于5%,准确度(RE)小于10%。通过一系列硫化物矿石标准物质进行方法验证,检测结果基本都在标准值的误差范围内,符合地质矿产开发的要求。方法简单,同时测定元素较多,线性范围宽,检出限低,尤其有利于硫化物矿石中的亲硫元素As、Ag、Hg的分析,实用性强。
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关键词:
- 铁铜铅锌硫化物矿石 /
- 电感耦合等离子体发射光谱法 /
- 王水溶样
Abstract: A method is presented in this paper for examining sulphide ores, in order to determine Cu, Pb, Zn, As, Ag, Cd, Hg and Mo within Fe, Cu, Pb and Zn contained in the ores. This method utilizes Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) with aqua regia digestion. The technique for sample dissolution and measuring conditions is also presented. The accuracy and precision of the method were examined by analyzing reference materials GBW07162 (multi-metal lean ore) and GBW07164 (multi-metal ore). The test results indicate that the relative standard deviation (RSD, n=11) of most elemental components is less than 5% and the accuracy (RE) is less than 10% for most elements. The method was validated by different reference materials and the results were in good agreement with the certified values, thereby meeting the requirements of mineral exploitation. The method has the advantage of providing a simple, simultaneous determination of multiple elements, along with having a wide linearity range and low detection limit, especially for the determination of As, Ag and Hg.-
Keywords:
- iron-copper-lead-zinc /
- sulfide /
- ores
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