煤中痕量溴的分析测试方法研究进展
Recent Progress in Analytical Methods of Trace Bromine in Coals
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摘要: 综述了近年来国内外煤中痕量溴测定方法的研究进展,介绍了间接分析法和直接分析法的基本特点和原理。间接分析法是先用高温热水解法、碱熔法或微波处理法等消解煤样品,使煤中溴进入溶液中,再用离子色谱法、电感耦合等离子体质谱法等测定煤消解液中溴的含量。直接分析法是用X射线荧光光谱法或中子活性法直接测定固体煤中溴的含量。对各种测试方法的适用性、存在问题及发展方向进行了比较和评述。Abstract: Recent progress of analytical methods for the determination of trace bromine in coal samples, including direct and indirect methods, were summarized in this paper. In indirect analytical method, coal sample was digested with high temperature hydrolysis, alkali-fusion or microwave digestion and then the bromine in sample solution was determined by ion chromatography (IC) or inductively coupled plasma-mass spectrometry (ICP-MS). In direct analytical method, X-ray fluorescence spectrometry (XRF) and neutron act vation analysis (NAA) are used to directly determine the bromine in coal samples. The basic characteristics and theory of each method are introduced. The applicability, existent problems and further development of the methods are also discussed.
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Keywords:
- coal /
- bromine /
- digestion /
- determination /
- progress
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Kabata-Pendias, Pendias. Trace elements in soils and plants [M]. CRC Press, 2000. Kabata-Pendias, Pendias. Trace elements in soils and plants [M]. CRC Press, 2000.
Wisniak J. The history of bromine form discovery to commodity [J]. Indian Journal of Chemical Technology, 2002(9): 263-271. Wisniak J. The history of bromine form discovery to commodity [J]. Indian Journal of Chemical Technology, 2002(9): 263-271.
Orlando J J. Atmospheric chemistry of organic bromine and iodine compounds [M]. The Handbook of Environmental Chemistry. Gribble G W,Edite, 2003:253-299. Orlando J J. Atmospheric chemistry of organic bromine and iodine compounds [M]. The Handbook of Environmental Chemistry. Gribble G W,Edite, 2003:253-299.
Aiuppa C, Federico A, Franco G,Giudice S,Gurrieri. Emission of bromine and iodine from Mount Etna Volcano[J]. Geochemistry Geophysics Geosystems, 2005, 10: 1029. Aiuppa C, Federico A, Franco G,Giudice S,Gurrieri. Emission of bromine and iodine from Mount Etna Volcano[J]. Geochemistry Geophysics Geosystems, 2005, 10: 1029.
Hattori T,Hurakami Y. Canodian g of chen[M].Eug,1974,52:601. Hattori T,Hurakami Y. Canodian g of chen[M].Eug,1974,52:601.
Michalakos P M, Robinson R C, Tang Y. Catalyst deactivation in the cracking of hexadecane and commercial FCC feed as studied by microactivity test multiple cold trap technique [J]. Catal Today,1998, 46:13. Michalakos P M, Robinson R C, Tang Y. Catalyst deactivation in the cracking of hexadecane and commercial FCC feed as studied by microactivity test multiple cold trap technique [J]. Catal Today,1998, 46:13.
Dimitriou A, Tsoukali H. Methyl bromide and bromide ion in soil after experimental greenhouse fumigation[J].Bulletin of Environmental Contamination and Toxicology,1998,61: 695-701. Dimitriou A, Tsoukali H. Methyl bromide and bromide ion in soil after experimental greenhouse fumigation[J].Bulletin of Environmental Contamination and Toxicology,1998,61: 695-701.
Mino Y, Yukita M. Detection of high levels of bromine in vegetables using X-ray fluorescence spectrometry [J]. Journal of Health Science, 2005,51(3):365-368. Mino Y, Yukita M. Detection of high levels of bromine in vegetables using X-ray fluorescence spectrometry [J]. Journal of Health Science, 2005,51(3):365-368.
徐明厚,郑楚光,冯荣,乔瑜,晏荣.煤燃烧过程中痕量元素排放的研究现状[J].中国电机工程学报[J].2001,21(10):3-38. Bettinelli M. Determination of chlorine, fluorine, bromine, and iodine in coals with ICP-MS and IC [J]. Atomic Spectroscopy,2002,23(4):105-110. Bettinelli M. Determination of chlorine, fluorine, bromine, and iodine in coals with ICP-MS and IC [J]. Atomic Spectroscopy,2002,23(4):105-110.
érico M M Flores, Márcia F Mesko. Determination of halogens in coal after digestion using the microwave-induced combustion technique[J].Analytical Chemi-stry,2008, 80:1865-1870. érico M M Flores, Márcia F Mesko. Determination of halogens in coal after digestion using the microwave-induced combustion technique[J].Analytical Chemi-stry,2008, 80:1865-1870.
Zhuang Y, Chen C, Timpe R, Pavlish J. Investiga-tions on bromine corrosion associated with mercury control technologies in coal flue gas[J]. Fuel, 2009,88:1692-1697. Zhuang Y, Chen C, Timpe R, Pavlish J. Investiga-tions on bromine corrosion associated with mercury control technologies in coal flue gas[J]. Fuel, 2009,88:1692-1697.
Valkovic. Trace elements in coal [M]. Boca Raton, 1983:I. 210,II. 281. Valkovic. Trace elements in coal [M]. Boca Raton, 1983:I. 210,II. 281.
Yudovich Y E, Ketris M P, Merts A V. Trace ele-ments in fossil coals[M].Leningrad:Nauka Science Publishing House,1985:239. Yudovich Y E, Ketris M P, Merts A V. Trace ele-ments in fossil coals[M].Leningrad:Nauka Science Publishing House,1985:239.
Swaine. Trace elements in coal [M].London:Butterworths,1990:278. Swaine. Trace elements in coal [M].London:Butterworths,1990:278.
赵继尧,唐修义,黄文辉.中国煤中微量元素的丰度[J].中国煤田地质,2002,14(Z1):5-17. Finkelman R B. Modes of occurrence of potentially hazardous elements in coal: Levels of confidence[J]. Fuel Processing Technology,1994, 39:21-34. Finkelman R B. Modes of occurrence of potentially hazardous elements in coal: Levels of confidence[J]. Fuel Processing Technology,1994, 39:21-34.
Finkelman R B. Trace and minor elements in coal [M].New York: Plenum Press, 1993: 593-607. Finkelman R B. Trace and minor elements in coal [M].New York: Plenum Press, 1993: 593-607.
Vassilev S V, Eskenazy G M, Vassilev C G. Contents, modes of occurrence and origin of chlorine and bromine in coal[J].Fuel,2000,79:903-921. Vassilev S V, Eskenazy G M, Vassilev C G. Contents, modes of occurrence and origin of chlorine and bromine in coal[J].Fuel,2000,79:903-921.
ASTM. Standard test method for chlorine in coal[S].2002: 2361-2362. ASTM. Standard test method for chlorine in coal[S].2002: 2361-2362.
齐庆杰,刘建忠,周俊虎,曹欣玉,岑可法.煤中微量元素氟测定方法的研究进展[J].煤炭转化,2000,23(2):7-11. ASTM. Standard test method for total fluorine in coal by the oxygen bomb combustion/ion selective electrode method[S]. 2002: 3761-3796. ASTM. Standard test method for total fluorine in coal by the oxygen bomb combustion/ion selective electrode method[S]. 2002: 3761-3796.
Godbeer C, Swaine D J. Fluorine in Australian Coals [J]. Fuel,1987,96:794-798. Godbeer C, Swaine D J. Fluorine in Australian Coals [J]. Fuel,1987,96:794-798.
Wu D S, Deng H W, Wang W Y, Xiao H Y. Catalytic spectrophotometric determination of iodine in coal by pyrohydrolysis decomposition[J]. Analytica Chimica Acta, 2000, 601: 183-188. Wu D S, Deng H W, Wang W Y, Xiao H Y. Catalytic spectrophotometric determination of iodine in coal by pyrohydrolysis decomposition[J]. Analytica Chimica Acta, 2000, 601: 183-188.
Blackwell P A, Cave M R, Davis A E, Malik S A. Determination of chlorine and bromine in rocks by alkaline fusion with ion chromatography detection[J]. Journal of Chromatography A, 1997, 770:93-98. Blackwell P A, Cave M R, Davis A E, Malik S A. Determination of chlorine and bromine in rocks by alkaline fusion with ion chromatography detection[J]. Journal of Chromatography A, 1997, 770:93-98.
Juliana S F Pereira, Liange O Diehl, Fábio A Duarte. Chloride determination by ion chromatography in petroleum coke after digestion by microwave-induced combustion [J]. Journal of Chromatography A,2008, 1213(2):249-252. Juliana S F Pereira, Liange O Diehl, Fábio A Duarte. Chloride determination by ion chromatography in petroleum coke after digestion by microwave-induced combustion [J]. Journal of Chromatography A,2008, 1213(2):249-252.
Dieter Florian, Günter Knapp. High-temperature, microwave-assisted UV digestion: A promising sample preparation technique for trace element analysis[J]. Analytical Chemistry,2001,73(7):1515-1520. Dieter Florian, Günter Knapp. High-temperature, microwave-assisted UV digestion: A promising sample preparation technique for trace element analysis[J]. Analytical Chemistry,2001,73(7):1515-1520.
Mesko M F, Moraes D P, Barin J S, Dressler V L, Knapp G, Flores E M M. Digestion of biological materials using the microwave-assisted sample combustion technique[J]. Microchem Journal,2006, 82:183-188. Mesko M F, Moraes D P, Barin J S, Dressler V L, Knapp G, Flores E M M. Digestion of biological materials using the microwave-assisted sample combustion technique[J]. Microchem Journal,2006, 82:183-188.
Moraes D P, Mesko M F, Mello P A, Paniz J N G, Dressler V L, Knapp G, Flores E M M. Application of microwave induced combustion in closed vessels for carbon black-containing elastomers decomposition [J]. Spectrochim Acta: Part B,2007, 62:1065-1071. Moraes D P, Mesko M F, Mello P A, Paniz J N G, Dressler V L, Knapp G, Flores E M M. Application of microwave induced combustion in closed vessels for carbon black-containing elastomers decomposition [J]. Spectrochim Acta: Part B,2007, 62:1065-1071.
Mester Zoltan, Sturgeon Ralph E. Sample preparation for trace element analysis[M].Amsterdam the Netherlands, 2003:683-719. Mester Zoltan, Sturgeon Ralph E. Sample preparation for trace element analysis[M].Amsterdam the Netherlands, 2003:683-719.
高运川,高勤芬,孙明星,朱志秀,陈宗宏.电感耦合等离子体-质谱同时测定煤、焦中砷、溴、碘[J].分析化学,2007,35(8):1175-1178. Evans J R, Sellars G A, Johnson R G. Analysis of eight argonne premium coal samples by X-ray fluorescence spectrometry[J].Energy Fuel,1990, 4:440. Evans J R, Sellars G A, Johnson R G. Analysis of eight argonne premium coal samples by X-ray fluorescence spectrometry[J].Energy Fuel,1990, 4:440.
Pianetta P, Baur K, Singh A, Brennan S, Kerner J, Wherho J, Wang J. Application of synchrotron radiation to TXFR analysis of metal contamination on silicon wafer surfaces[J]. Thin Solid Film,2000, 373:222. Pianetta P, Baur K, Singh A, Brennan S, Kerner J, Wherho J, Wang J. Application of synchrotron radiation to TXFR analysis of metal contamination on silicon wafer surfaces[J]. Thin Solid Film,2000, 373:222.
孟韵,王彝,张军营,钟秦.煤及其燃烧产物中无机组分分析方法比较[J].煤炭转化,2004,27(3):6-11. Eskenazy G, Vassilev S, Karaivanova E. Chlorine and bromine in the Pirin coal deposit, Bulgaria[J].Review of the Bulgarian Geological Society, 1998,59(2):67-72. Eskenazy G, Vassilev S, Karaivanova E. Chlorine and bromine in the Pirin coal deposit, Bulgaria[J].Review of the Bulgarian Geological Society, 1998,59(2):67-72.
Roos-Barraclough F, Martinez-Cortizas A, Eduardo Garc a, Rodeja W Shotyk. A 14500 year record of the accumulation of atmospheric mercury in peat: Volcanic signals, anthropogenic influences and a correlation to bromine accumulation[J].Earth and Planetary Science Letters,2002,202:435-451. Roos-Barraclough F, Martinez-Cortizas A, Eduardo Garc a, Rodeja W Shotyk. A 14500 year record of the accumulation of atmospheric mercury in peat: Volcanic signals, anthropogenic influences and a correlation to bromine accumulation[J].Earth and Planetary Science Letters,2002,202:435-451.
Andersson M, Olin A. Determination of bromine, chlorine, sulphur and phosphorus in peat by X-ray fluorescence spectrometry combined with single-element and multi-element standard addition[J].Talanta,1990,37(2):185-191. Andersson M, Olin A. Determination of bromine, chlorine, sulphur and phosphorus in peat by X-ray fluorescence spectrometry combined with single-element and multi-element standard addition[J].Talanta,1990,37(2):185-191.
Senior C L, Zeng T, Che J, Ames M R, Sarofim A F, Olmez I. Distribution of trace elements in selected pulverized coals as a function of particle size and density[J].Fuel Process Technology,2000, 63:216. Senior C L, Zeng T, Che J, Ames M R, Sarofim A F, Olmez I. Distribution of trace elements in selected pulverized coals as a function of particle size and density[J].Fuel Process Technology,2000, 63:216.
Landsberger S, Vermette V G, Wolfe M, Powell M A. Determination of halogens in coal using thermal and epithermal neutron activation analysis[J].Journal of Coal Quality, 1989, 7-12:95-97. Landsberger S, Vermette V G, Wolfe M, Powell M A. Determination of halogens in coal using thermal and epithermal neutron activation analysis[J].Journal of Coal Quality, 1989, 7-12:95-97.
Ebihara M, Ozaki H, Kato F, Nakahara H. Deter-mination of chlorine, bromine and iodine in rock samples by radiochemical neutron activation analysis[J].Journal of Radioanalytical and Nuclear Chemistry,1997,216(1):107-112. Ebihara M, Ozaki H, Kato F, Nakahara H. Deter-mination of chlorine, bromine and iodine in rock samples by radiochemical neutron activation analysis[J].Journal of Radioanalytical and Nuclear Chemistry,1997,216(1):107-112.
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