水环境中磷的赋存形态及其分析方法研究进展
Research Progress on Speciation Analysis of Phosphorus in Aquatic Environment
-
摘要: 文章归纳总结了近年来国内外在水环境中磷的赋存形态这一领域的研究进展,着重介绍了水体和沉积物中磷赋存形态的分类、不同形态磷的前处理及其提取、分析测定方法,概括了其研究现状,并对以后的发展趋势作了展望。这对于深入揭示水环境中磷的赋存形态及其环境与生物地球化学循环有着重要的指导意义。Abstract: Progresses on study of phosphorus species and its speciation analysis in the aquatic environment were reviewed. The classification on phosphorus species in aquatic environment and sediments, pretreatment and sequential extraction procedures for various phosphorus species and the analytical methods for phosphorus species were emphatically introduced. The applications for the phosphorus speciation analysis were summarized and the development trends in this area are also prospected. In all, it is significantly important for understanding the phosphorus species existed and the biogeochemical cycle of phosphorus in aquatic environment. 53 references were cited.
-
Keywords:
- aquatic /
- environment /
- sediment /
- phosphorus
-
-
王琦,姜霞,金相灿,徐玉慧.太湖不同营养水平湖区沉积物磷形态与生物可利用磷的分布及相互关系[J].湖泊科学,2006,18(2):120-126. 徐青,吴怡,廖梦霞,邓天龙.水环境中氮磷分析方法研究进展[J].岩矿测试,2008,27(2):103-107. Lawrence M. Reviving dead zone[J].Scientific American,2006,295:79-85. Lawrence M. Reviving dead zone[J].Scientific American,2006,295:79-85.
Shen P P, Shi Q, Hua Z C, Kong F X, Wang Z G, Zhuang S X, Chen D C. Analysis of microcystins in cyanobacteria blooms and surface water samples from Meiliang Bay, Taihu Lake, China[J].Environmental International,2003, 5:641-647. Shen P P, Shi Q, Hua Z C, Kong F X, Wang Z G, Zhuang S X, Chen D C. Analysis of microcystins in cyanobacteria blooms and surface water samples from Meiliang Bay, Taihu Lake, China[J].Environmental International,2003, 5:641-647.
夏学惠,东野脉兴,周建民,田升平,张灼,彭彦华.滇池现代沉积物中磷的地球化学及其对环境影响[J].沉积学报,2002,20(3):416-420. 颜昌宙,金相灿,赵景柱,沈兵,李宁波,黄昌筑,熊仲华.云南洱海的生态保护及可持续利用对策[J].环境科学,2005,26(5):38-42. 赵亮,魏皓,冯士筰.渤海氮磷营养盐的循环和收支[J].环境科学,2002,23(1):79-81. 沈志良,刘群,张淑美,苗辉,张平.长江和长江口高含量无机氮的主要控制因素[J].海洋与湖沼,2001,32(5):465-473. Lee G F.Role of phosphorus in eutrophication and diffuse source control[J].Water Research,1973,7:111-128. Lee G F.Role of phosphorus in eutrophication and diffuse source control[J].Water Research,1973,7:111-128.
Ryther J H, Yentsch C S. The estimation of phytoplankton production in the ocean from chlorophyll and light data[J]. Limnology and Oceanography, 1957, 2:281-286. Ryther J H, Yentsch C S. The estimation of phytoplankton production in the ocean from chlorophyll and light data[J]. Limnology and Oceanography, 1957, 2:281-286.
Lund J W. Eutrophication[J].Nature, 1967, 6:557-558. Lund J W. Eutrophication[J].Nature, 1967, 6:557-558.
Warner F, Cremer, Warner. International association on water pollution research phosphorus in fresh water and the marine environment 11-13 April 1972[J].Water Research,1973, 7:1. Warner F, Cremer, Warner. International association on water pollution research phosphorus in fresh water and the marine environment 11-13 April 1972[J].Water Research,1973, 7:1.
Sly P G.Freshwater sediment interaction[M].New York: Springer-Verlag Press,1986:521. Sly P G.Freshwater sediment interaction[M].New York: Springer-Verlag Press,1986:521.
Berner K, Berner R A. The global water cycle[M].Englewood: Prentice-Hall Press, 1987:231-240. Berner K, Berner R A. The global water cycle[M].Englewood: Prentice-Hall Press, 1987:231-240.
Wang Z J, Giovanoli F, El-Ghobary H, El-Vernet J P. A speciation study of phosphorus in the interstitial water of Lake Geneva(Switzerland) [M]//Freshwater sediment interaction.Sly P G, editor. New York: Springer-Verlag Press, 1986:175-180. Wang Z J, Giovanoli F, El-Ghobary H, El-Vernet J P. A speciation study of phosphorus in the interstitial water of Lake Geneva(Switzerland) [M]//Freshwater sediment interaction.Sly P G, editor. New York: Springer-Verlag Press, 1986:175-180.
Jarvie H P, Whitton B A, Neal C. Nitrogen and phosphorus in east coast British rivers: Speciation, sources and biological significance[J].The Science of the Total Environment, 1998,210-211:79-109. Jarvie H P, Whitton B A, Neal C. Nitrogen and phosphorus in east coast British rivers: Speciation, sources and biological significance[J].The Science of the Total Environment, 1998,210-211:79-109.
Evans D J, Johnes P J. Physico-chemical controls on phosphorus cycling in two lowland Streams Part 1—The water column [J]. The Science of the Total Environment,2004,329:145-163. Evans D J, Johnes P J. Physico-chemical controls on phosphorus cycling in two lowland Streams Part 1—The water column [J]. The Science of the Total Environment,2004,329:145-163.
Cooper D M, House W A, Reynolds B. The phosph-orus budget of the Thame catchment, Oxfordshire: 2. Modelling[J].The Science of the Total Environment,2002,282-283:435-457. Cooper D M, House W A, Reynolds B. The phosph-orus budget of the Thame catchment, Oxfordshire: 2. Modelling[J].The Science of the Total Environment,2002,282-283:435-457.
Solórzano L, Strickland J D. Polyphosphate in seawater[J].Limnology and Oceanography, 1968, 13:515-518. Solórzano L, Strickland J D. Polyphosphate in seawater[J].Limnology and Oceanography, 1968, 13:515-518.
Tue-Ngeun O, Ellis P, McKelvie I D,Worsfold P, Jakmunee J, Grudpan K. Determination of dissolved reactive phosphorus(DRP) and dissolved organic phosphorus(DOP) in natural waters by the use of rapid sequenced reagent injection flow analysis[J].Talanta, 2005, 66:453-460. Tue-Ngeun O, Ellis P, McKelvie I D,Worsfold P, Jakmunee J, Grudpan K. Determination of dissolved reactive phosphorus(DRP) and dissolved organic phosphorus(DOP) in natural waters by the use of rapid sequenced reagent injection flow analysis[J].Talanta, 2005, 66:453-460.
Fang T H. Phosphorus speciation and budget of the East China Sea[J].Continental Shelf Research, 2004, 24:1285-1299. Fang T H. Phosphorus speciation and budget of the East China Sea[J].Continental Shelf Research, 2004, 24:1285-1299.
Yoshimura T, Nishioka J, Saito H, Takeda S, Tsuda A, Wells M L. Distributions of particulate and dissolved organic and inorganic phosphorus in North Pacific surface waters[J].Marine Chemistry, 2007, 103:112-121. Yoshimura T, Nishioka J, Saito H, Takeda S, Tsuda A, Wells M L. Distributions of particulate and dissolved organic and inorganic phosphorus in North Pacific surface waters[J].Marine Chemistry, 2007, 103:112-121.
Brandes J A, Ingall E, Paterson D.Characterization of minerals and organic phosphorus species in marine sediments using soft X-ray fluorescence spectromicroscopy[J].Marine Chemistry,2007,103(3-4):250-265. Brandes J A, Ingall E, Paterson D.Characterization of minerals and organic phosphorus species in marine sediments using soft X-ray fluorescence spectromicroscopy[J].Marine Chemistry,2007,103(3-4):250-265.
Benitez-Nelson C R. The biogeochemical cycling of phosphorus in marine systems[J].Earth-Science Reviews,2000,51(1-4):109-135. Benitez-Nelson C R. The biogeochemical cycling of phosphorus in marine systems[J].Earth-Science Reviews,2000,51(1-4):109-135.
Kolowith L C, Ingall E, Benner R. Composition and cycling of marine organic phosphorus[J].Limnology and Oceanography,2001,46(2):309-320. Kolowith L C, Ingall E, Benner R. Composition and cycling of marine organic phosphorus[J].Limnology and Oceanography,2001,46(2):309-320.
Clark L L,Ingall E,Benner R. Marine organic phosph-orus cycling: novel insights from nuclear magnetic resonance[J].American Journal of Science,1999,299(7-9):724-737. Clark L L,Ingall E,Benner R. Marine organic phosph-orus cycling: novel insights from nuclear magnetic resonance[J].American Journal of Science,1999,299(7-9):724-737.
Barlow J P, Glase M S. Partitioning of phosphorus between particles and water in a river outflow, in: Sly P G (Editor), Freshwater sediment interaction[M]. Hague: Junk Publishers,1982:253-260. Barlow J P, Glase M S. Partitioning of phosphorus between particles and water in a river outflow, in: Sly P G (Editor), Freshwater sediment interaction[M]. Hague: Junk Publishers,1982:253-260.
Rinker K R, Powell R T. Dissolved organic phosph-orus in the Mississippi River plume during spring and fall 2002[J].Marine Chemistry,2006,102:170-179. Rinker K R, Powell R T. Dissolved organic phosph-orus in the Mississippi River plume during spring and fall 2002[J].Marine Chemistry,2006,102:170-179.
Benitez-Nelson C R, O'Neill L, Kolowith L C, Pellechia P, Thunell R. Phosphonates and particulate organic phosphorus cycling in an anoxic marine basin[J].Limnology and Oceanography, 2004, 49:1593-1604. Benitez-Nelson C R, O'Neill L, Kolowith L C, Pellechia P, Thunell R. Phosphonates and particulate organic phosphorus cycling in an anoxic marine basin[J].Limnology and Oceanography, 2004, 49:1593-1604.
Hens M, Merckx R.The role of colloidal particles in the speciation and analysis of "dissolved" phosphorus[J]. Water Research, 2002, 36:1483-1492. Hens M, Merckx R.The role of colloidal particles in the speciation and analysis of "dissolved" phosphorus[J]. Water Research, 2002, 36:1483-1492.
Van der Zee,Roevros N C,Chou L.Phosphorus speciation, transformation and retention in the Scheldt estuary(Belgium/The Netherlands) from the freshwater tidal limits to the North Sea[J]. Marine Chemistry,2007,106:76-91. Van der Zee,Roevros N C,Chou L.Phosphorus speciation, transformation and retention in the Scheldt estuary(Belgium/The Netherlands) from the freshwater tidal limits to the North Sea[J]. Marine Chemistry,2007,106:76-91.
Hieltjes A H, Lijklema L. Fractionation of inorganic phosphorus in calcareous sediments[J].Journal of Environmental Quality,1980, 8:130-132. Hieltjes A H, Lijklema L. Fractionation of inorganic phosphorus in calcareous sediments[J].Journal of Environmental Quality,1980, 8:130-132.
Ruttenberg K C. Development of a sequential extrac-tion method for different forms of phosphorus in marine sediments[J].Limnology and Oceanography,1992, 37(7):1460-1482. Ruttenberg K C. Development of a sequential extrac-tion method for different forms of phosphorus in marine sediments[J].Limnology and Oceanography,1992, 37(7):1460-1482.
Golterman H L.Fractionation of sediment phosphate with chelating compounds: a simplification and comparison with other methods[J]. Hydrobiologia, 1996, 364(1):99-104. Golterman H L.Fractionation of sediment phosphate with chelating compounds: a simplification and comparison with other methods[J]. Hydrobiologia, 1996, 364(1):99-104.
朱广伟,秦伯强,张路.长江中下游湖泊沉积物中磷的形态及藻类可利用量[J].中国科学:D辑,2005,35:24-32. 胡凯,柯鹏振,吴永红, 陈晓国,沈银武,刘剑彤.高原浅水湖泊沉积物中磷、氮形态化学研究[J].长江流域资源与环境,2005,14(4):507-511. 胡俊,丰民义,吴永红,刘剑彤.沉水植物对沉积物中磷赋存形态影响的初步研究[J].环境化学,2006,25(1):28-31. 李军,刘丛强, 王仕禄,朱兆洲,周志华,肖化云.太湖五里湖表层沉积物中不同形态磷的分布特征[J].矿物学报,2004,24(4):405-410. 赵颖,王国秀,章北平.典型城内过富营养湖泊沉积物和间隙水中各形态磷的相关性研究[J].长江流域资源与环境,2006,15(4):490-494. Grasshoff K, Ehrhardt M, Kremling K. Methods of Seawater Analysis[M].Basel: Verlag Chemie,1983. Grasshoff K, Ehrhardt M, Kremling K. Methods of Seawater Analysis[M].Basel: Verlag Chemie,1983.
戚晓红.中国近海部分典型海域磷的生物地球化学研究 .青岛:中国海洋大学,2005. Neal C, Neal M, Wickham H. Phosphate measurement in natural waters: two examples of analytical problems associated with silica interference using phospho-molybdic acid methodologies[J].The Science of the Total Environment, 2000, 251-252:511-522. Neal C, Neal M, Wickham H. Phosphate measurement in natural waters: two examples of analytical problems associated with silica interference using phospho-molybdic acid methodologies[J].The Science of the Total Environment, 2000, 251-252:511-522.
Liu S M, Zhang J, Li D J. Phosphorus cycling in sediments of the Bohai and Yellow Seas[J].Estuarine, Coastal and Shelf Science, 2004, 59:209-218. Liu S M, Zhang J, Li D J. Phosphorus cycling in sediments of the Bohai and Yellow Seas[J].Estuarine, Coastal and Shelf Science, 2004, 59:209-218.
Chang S C, Jackson M L. Fractionation of soil phosphorus[J]. Soil Science,1957,84:133-144. Chang S C, Jackson M L. Fractionation of soil phosphorus[J]. Soil Science,1957,84:133-144.
张斌亮.浅水湖泊沉积物-水界面磷的行为特征与环境风险评价 .上海:华东师范大学,2004. 魏复盛.水和废水监测分析方法[M].4版.北京:中国环境科学出版社,2002. Murphy J, Riley J R.A modified single solution method for the determination of phosphate in natural waters[J]. Analytica Chimica Acta, 1962, 27:31-36. Murphy J, Riley J R.A modified single solution method for the determination of phosphate in natural waters[J]. Analytica Chimica Acta, 1962, 27:31-36.
Eisenreich S J, Bannerman R T, Armstrong D E.A simplified phosphorus analysis technique [J]. Environmental Letters, 1975, 9:43-53. Eisenreich S J, Bannerman R T, Armstrong D E.A simplified phosphorus analysis technique [J]. Environmental Letters, 1975, 9:43-53.
刘浏,刘晓端,徐清,葛晓立,王英华.密云水库沉积物中磷的形态和分布特征[J].岩矿测试,2003, 22(2):81-85. Liu J Y, Wang H, Yang H J, Ma Y J, Cai O C. Detection of phosphorus species in sediments of artificial landscape lakes in China by fractionation and phosphorus-31 nuclear magnetic resonance spectroscopy[J]. Environmental Pollution, 2009, 157:49-56. Liu J Y, Wang H, Yang H J, Ma Y J, Cai O C. Detection of phosphorus species in sediments of artificial landscape lakes in China by fractionation and phosphorus-31 nuclear magnetic resonance spectroscopy[J]. Environmental Pollution, 2009, 157:49-56.
Worsfold P J, Monbet P, Tappin A D, Fitzsimons M F, Stiles D A, McKelvie I D. Characterisation and quantification of organic phosphorus and organic nitrogen components in aquatic systems[J].Analytica Chimica Acta, 2008,624(1):37-58. Worsfold P J, Monbet P, Tappin A D, Fitzsimons M F, Stiles D A, McKelvie I D. Characterisation and quantification of organic phosphorus and organic nitrogen components in aquatic systems[J].Analytica Chimica Acta, 2008,624(1):37-58.
Sannigrahi P,Ingall E D,Benner R. Nature and dynamics of phosphorus containing components of marine dissolved and particulate organic matter[J]. Geochimica et Cosmochimica Acta, 2006, 70:5868-5882. Sannigrahi P,Ingall E D,Benner R. Nature and dynamics of phosphorus containing components of marine dissolved and particulate organic matter[J]. Geochimica et Cosmochimica Acta, 2006, 70:5868-5882.
De Brabandere H, Danielsson R, Sjberg P J, Ahlgren J, Rydin E, Waldebck M. Sediment extraction and clean-up for organic phosphorus analysis by electrospray ionization tandem mass spectrometry[J]. Talanta, 2008, 74: 1175-1183. De Brabandere H, Danielsson R, Sjberg P J, Ahlgren J, Rydin E, Waldebck M. Sediment extraction and clean-up for organic phosphorus analysis by electrospray ionization tandem mass spectrometry[J]. Talanta, 2008, 74: 1175-1183.
Brandes J A, Ingall E, Paterson D. Characterization of mineral and organic phosphorus species in marine sediments using soft X-ray fluorescence spectromicroscopy[J]. Marine Chemistry, 2007, 103: 250-265. Brandes J A, Ingall E, Paterson D. Characterization of mineral and organic phosphorus species in marine sediments using soft X-ray fluorescence spectromicroscopy[J]. Marine Chemistry, 2007, 103: 250-265.
Estela J M, Cerd V. Flow analysis techniques for phosphorus:an overview[J].Talanta,2005, 66:307-331. Estela J M, Cerd V. Flow analysis techniques for phosphorus:an overview[J].Talanta,2005, 66:307-331.
Newman R H, Tate K R. Soil phosphorus characteri-zation by 31P nuclear magnetic resonance[J]. Communications in Soil Science and Plant Analysis, 1980, 11: 835-842. Newman R H, Tate K R. Soil phosphorus characteri-zation by 31P nuclear magnetic resonance[J]. Communications in Soil Science and Plant Analysis, 1980, 11: 835-842.
Bai X L, Ding S M, Fan C X, Liu T, Shi D, Zhang L. Organic phosphorus species in surface sediments of a large, shallow, eutrophic lake, Lake Taihu, China[J]. Environmental Pollution, 2009, 157: 2507-2513. Bai X L, Ding S M, Fan C X, Liu T, Shi D, Zhang L. Organic phosphorus species in surface sediments of a large, shallow, eutrophic lake, Lake Taihu, China[J]. Environmental Pollution, 2009, 157: 2507-2513.
Nanny M A, Minear R A.Characterization of soluble unreactive phosphorus using 31P nuclear magnetic resonance spectroscopy[J]. Marine Geology,1997,139: 77-94. Nanny M A, Minear R A.Characterization of soluble unreactive phosphorus using 31P nuclear magnetic resonance spectroscopy[J]. Marine Geology,1997,139: 77-94.
Reitzel K, Ahlgren J, Gogoll A, Henning S J, Rydin E.Characterization of phosphorus in sequential extracts from lake sediments using 31P nuclear magnetic resonance spectroscopy[J].Canadian Journal of Fisheries and Aquatic Sciences, 2006, 63: 1686-1699. Reitzel K, Ahlgren J, Gogoll A, Henning S J, Rydin E.Characterization of phosphorus in sequential extracts from lake sediments using 31P nuclear magnetic resonance spectroscopy[J].Canadian Journal of Fisheries and Aquatic Sciences, 2006, 63: 1686-1699.
Chang S Y, Tseng W L, Mallipattu S, Chang H T. Determination of small phosphorus-containing com-pounds by capillary electrophoresis[J].Talana,2005,66: 411-421. Chang S Y, Tseng W L, Mallipattu S, Chang H T. Determination of small phosphorus-containing com-pounds by capillary electrophoresis[J].Talana,2005,66: 411-421.
Hanrahan G, Salmassi T, Khachikian C, Foser K L. Reduced inorganic phosphorus in the natural environment significance, speciation and determination[J].Talanta,2005,66:435-444. Hanrahan G, Salmassi T, Khachikian C, Foser K L. Reduced inorganic phosphorus in the natural environment significance, speciation and determination[J].Talanta,2005,66:435-444.
计量
- 文章访问数: 1970
- HTML全文浏览量: 39
- PDF下载量: 2460
下载:
京公网安备 11010202008159号