密闭消解电感耦合等离子体质谱法同时测定苹果中多元素含量及其分布
Simultaneous Determination of Multi-elements in Apples by Inductively Coupled Plasma-Mass Spectrometry with Pressurized Acid Digestion
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摘要: 采用电感耦合等离子体质谱,硝酸-氢氟酸-双氧水增压密闭消解样品,实现了苹果中43种元素含量的同时测定。比较了采取干样和鲜样进行多元素同时测定时的相关性,干样和鲜样中元素比值为0.9~1.1,证实了干样和鲜样测定结果具有很好的一致性。各元素的检出限在0.0009~2.8620 μg/L,相对标准偏差为1.13%~3.45%。比较了不同元素在果皮和果肉中的分布,结果表明:果皮中的元素含量明显高于果肉,稀土元素在果皮富集明显。
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关键词:
- 密闭消解 /
- 电感耦合等离子体质谱法 /
- 苹果 /
- 元素分布
Abstract: A method for simultaneous determination of 43 elements in apples by inductively coupled plasma-mass spectrometry (ICP-MS) was proposed. The apple samples were digested in closed vessels with HNO3-HF-H2O2 mixed solvent. The fresh and dry samples from the same apple were used to evaluate the quality of analytical data. The ratios of determined values in fresh and dry samples were 0.9~1.1, which indicated that the analytical results were well consistent. The detection limits and the precision of the method were in the range of 0.0009~2.8620 μg/L and 1.13%~3.45% RSD, respectively. The proposed method has been used in the investigation of elemental distribution in apples and the results showed that the concentration of elements in apple skin was significantly higher than that in apple pulp, especially for rare earth elements.-
Keywords:
- pressurized /
- acid /
- digestion /
- inductively
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周国华,董岩翔,张建明.浙江省农业地质环境调查评价方法技术[M].北京:地质出版社,2007:158-160. Galani-Nikolakaki S, Kallithrakas-Kontos N, Katsanos A A.Trace element analysis of Cretan wines and wine products[J].The Science of the Total Environment,2002,285:155-163. Galani-Nikolakaki S, Kallithrakas-Kontos N, Katsanos A A.Trace element analysis of Cretan wines and wine products[J].The Science of the Total Environment,2002,285:155-163.
芮玉奎,郭晶,黄昆仑,金银花,罗云波.应用ICP-MS检测转Bt基因玉米中重金属含量[J].光谱学与光谱分析,2007,27(4):796-798. 王春枝,刘丽杰,朱福磊,许大志,徐冰.苹果苦痘病与果实内矿质养分平衡状况的相关性分析[J].北方园艺,2009,8:58-60. 琚彤军,刘普灵,石辉.稀土元素在作物体内的吸收及分布特征研究[J].中国稀土学,2002(20):163-167. 叶青.微波消解-原子吸收法初步分析葛根中微量元素与种植土质的相关性[J].岩矿测试,2006,25(4):387-390. Sass-Kiss A, Kiss J, Havadi B, Adanyi N.Multivariate statistical analysis of bitrtised wines of different origin[J].Food Chemistry,2000,110:742-750. Sass-Kiss A, Kiss J, Havadi B, Adanyi N.Multivariate statistical analysis of bitrtised wines of different origin[J].Food Chemistry,2000,110:742-750.
Marengo E, Aceto M. Statistical investigation of the differences in the distribution of metals in Nebbiolo-based wines[J].Food Chemistry, 2003,81:621-630. Marengo E, Aceto M. Statistical investigation of the differences in the distribution of metals in Nebbiolo-based wines[J].Food Chemistry, 2003,81:621-630.
关明,张连波,李茵萍,杜卫军.火焰原子吸收法测定天然蜂蜜中的锌含量[J].食品科学,2007,28(7):414-416. 李公海,沈崇钰,蒋原,吴斌,陈惠兰.石墨炉原子吸收直接测定蜂胶中铅[J].分析化学,2007,35(6):931. 代春吉,董文宾,梁西爱,苗晓洁.微波消解-原子荧光光谱法测定苹果中的汞[J].食品科技,2007,32(2):221-222. 李连平,范威,黄志勇,庄峙厦.蔬菜中硒总量及形态的氢化物发生-原子荧光光谱测定方法[J].光谱学与光谱分析,2008,28(12):2975-2978. Welna M,Klimpel M,Zymicki W. Investigation of major and trace elements and their distributions between lipid and non-lipid fractions in Brazil nuts by inductively coupled plasma atomic optical spectrometry[J].Food Chemistry,2008,111:1012-1015. Welna M,Klimpel M,Zymicki W. Investigation of major and trace elements and their distributions between lipid and non-lipid fractions in Brazil nuts by inductively coupled plasma atomic optical spectrometry[J].Food Chemistry,2008,111:1012-1015.
林立,杨彦丽,周谙非,田艳玲,张曼玲.微波消解-电感耦合等离子体发射光谱法分析食品中的总硼[J].岩矿测试,2008,27(1):21-24. Almeida C M R,Vasconcelos M T S D,Barbaste M.ICP-MS multi-element analysis of wine samples—A comparative study of the methodologies used in two laboratories[J].Analytical and Bioanalytical Chemistry ,2002,374:314-322. Almeida C M R,Vasconcelos M T S D,Barbaste M.ICP-MS multi-element analysis of wine samples—A comparative study of the methodologies used in two laboratories[J].Analytical and Bioanalytical Chemistry ,2002,374:314-322.
林立,陈光,陈玉红.电感耦合等离子体质谱法测定茶叶中的16种稀土元素[J].环境化学,2007,26(4):555-558 Lemes M, Wang F Y.Methyl mercury speciation in fish muscle by HPLC-ICP-MS following enzymatic hydrolysis[J].Journal of Analytical Atomic Spectro-metry,2009,24(5):663-668. Lemes M, Wang F Y.Methyl mercury speciation in fish muscle by HPLC-ICP-MS following enzymatic hydrolysis[J].Journal of Analytical Atomic Spectro-metry,2009,24(5):663-668.
刘庆阳,何滨,胡敬田,江桂斌.高效液相色谱与原子荧光光谱联用分析海产品中的甲基汞[J].分析试验室,2009,28(8):41-44. 李冰,杨红霞.电感耦合等离子体质谱原理和应用[M].北京:地质出版社,2005:7. 王小平.不同分解方法对ICP-AES测定植物样品中元素含量的影响[J].光谱学与光谱分析,2005,25(4):563-566.
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