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分流比对烃类单分子氢同位素分析的影响

李中平, 李立武, 陶明信, 王作栋, 王 广, 杜 丽, 张明峰, 石 磊

李中平, 李立武, 陶明信, 王作栋, 王 广, 杜 丽, 张明峰, 石 磊. 分流比对烃类单分子氢同位素分析的影响[J]. 岩矿测试, 2010, 29(3): 221-224.
引用本文: 李中平, 李立武, 陶明信, 王作栋, 王 广, 杜 丽, 张明峰, 石 磊. 分流比对烃类单分子氢同位素分析的影响[J]. 岩矿测试, 2010, 29(3): 221-224.
LI Zhong-ping, LI Li-wu, TAO Ming-xin, WANG Zuo-dong, WANG Guang, DU Li, ZHANG Ming-feng, SHI Lei. Effect of Split Ratio on Hydrogen Isotope Ratio Analysis for the Single Molecule Hydrocarbons[J]. Rock and Mineral Analysis, 2010, 29(3): 221-224.
Citation: LI Zhong-ping, LI Li-wu, TAO Ming-xin, WANG Zuo-dong, WANG Guang, DU Li, ZHANG Ming-feng, SHI Lei. Effect of Split Ratio on Hydrogen Isotope Ratio Analysis for the Single Molecule Hydrocarbons[J]. Rock and Mineral Analysis, 2010, 29(3): 221-224.

分流比对烃类单分子氢同位素分析的影响

基金项目: 

"中国科学院西部博士"项目资助

国家自然科学基金项目资助(40872096)

教育部重大项目资助(307007)

Effect of Split Ratio on Hydrogen Isotope Ratio Analysis for the Single Molecule Hydrocarbons

  • 摘要: 在单体烃的氢同位素系统测定中,以甲烷为样品,选择不同的分流比(0.1、0.5、1.0、2.0、5.0、10.0),采用气相色谱-高温热转换-同位素比率质谱对相应的氢同位素比值进行研究。结果表明,不同的分流比对峰形、出峰面积及单体烃的氢同位素值有不同程度的影响,总体上随着分流比的增大,峰宽及峰面积呈现指数方式递减;特别是当分流比较小(小于1)时,导致氢同位素值测定结果的不确定度增大;分流比较大时,氢同位素值趋于稳定。文章对造成这种现象的原因进行了分析,认为在单体烃的氢同位素的分析中,选择较大的分流比不会导致明显的同位素分馏,从而对样品分析更为有利。
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出版历程
  • 收稿日期:  2009-06-04
  • 修回日期:  2009-12-20

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