胶束电动毛细管色谱法测定海底表层沉积物中的苯系化合物
Determination of BTEX Compounds in Marine Shallow Sediments by Micellar Electrokinetic Capillary Chromatography
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摘要: 用胶束电动毛细管色谱法对海底表层沉积物中的苯系化合物进行了分析测定。采用57cm×50μm毛细管柱,以50mmol/L十二烷基硫酸钠-2.0mmol/L四硼酸钠溶液(pH9.16)作为操作缓冲溶液,并加入φ=20%的甲醇作为有机改性剂,电压25kV,检测波长200nm,15min内苯、甲苯、乙苯和二甲苯可获得良好的分离。用峰面积定量,线性范围为2~100mg/L,最小检测浓度分别为0.75mg/L苯,0.45mg/L甲苯,0.39mg/L乙苯,0.1mg/L邻-二甲苯,0.31mg/L对-二甲苯。将该法用