黄原酯棉富集分离—全差示光度法测定痕量银
Fully Differential Spectrophotometry of Trace Silver in Geological Samples after Preconcentration with Xanthated Cotton Fiber
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摘要: 在5—35%HClO_4介质中,0.1g黄原酯棉可定量吸附500μg Ag,灰化解脱后Ag回收率在99%以上。Ag-金试剂-OP络合物的显色条件是:pH为4.5—6.5,最大吸收波长505nm,摩尔吸光系数1.0×10~5,络合物组成是Ag:金试剂=1:4,Ag量在0—10μg/25ml范围内符合比尔定律。采用全差示分光光度法测定地质样品中的Ag,操作简单快速、灵敏度高、选择性好、测定范围宽.