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温度对沸石吸钾量检测的影响研究

Study on the Effect of Temperature on Potassium Uptake by Zeolite

  • 摘要: 沸石具有选择性吸附钾离子的特性,吸钾量是沸石应用中一项重要的物化性能,温度是影响吸钾量测量结果准确度的重要因素。在现有的吸钾量测试方法中,由于对测试温度的规定较为模糊,基本不作设定或只注明室温,而室温随季节变化较大,测试方法的准确度和精密度无法得到保证。为完善吸钾量的测试方法,本文研究了实际温度对沸石吸钾量的影响。结果表明,在试验的温度范围内(11.5~80℃),沸石样品的吸钾量与温度呈稳定且相对固定的负相关,由此提出了吸钾量计算公式:E20=Et+kt-t20)。根据该定量关系,本文提出吸钾量测试方法中需要明确规定吸钾量的测试温度为20℃;如果是在非20℃的实际温度下测量得到的吸钾量,可根据温度校正系数(k)转换到20℃条件下的吸钾量。这种吸钾量测试方法可在实际室温下进行,操作简单,无需使用控温装置;又能消除因时间和地域差异导致的室温波动的影响,使吸钾量测试结果具有更好的精密度和准确度。

     

    Abstract: Absorption of potassium ion selectively is a typical characteristic of zeolite. Potassium uptake is one of the important physical and chemical properties of zeolite, which is influenced by temperature. At present, the instruction about temperature in the test method of potassium uptake is not clearly defined, stated as room temperature only. However, room temperature is always changing with the season, hereby; the accuracy and precision of the test method are not guaranteed. This research discussed the effect of temperature on potassium uptake of zeolite in order to improve the test method on potassium uptake. It was found that there was a stable and fixed negative correlation between potassium uptake and temperature in a certain range of temperature (11.5-80℃ was researched in this article). The formula to calculate the potassium uptake is proposed to be E20=Et+k(t-t20). According to this quantitative relationship, it is suggested that the result of potassium uptake should be pointed to yield at 20℃. If the room temperature differs from 20℃, it should be transferred to the result at 20℃ by using the temperature correction coefficient (k). This test method of potassium uptake can be taken at the actual room temperature, which can be done without equipment to control the temperature conveniently. It can avoid the influence of room temperature changing because of the difference of time and area, so that the accuracy and precision of the test method improves.

     

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