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冀东平原区浅层地下水金属来源分析与环境健康风险评价

Analysis of Metal Sources in Shallow Groundwater and Environmental Health Risk Evaluation in the Jidong Plain Area

  • 摘要: 近年来地下水环境受到人类活动的影响,对人体健康带来潜在的风险。为探究地下水中金属元素对人体健康的影响,本文选择河北唐山市平原区为研究区,采集了该区64件浅层地下水样品,检测Fe、Mn等10种金属元素并分析其浓度特征,运用地学统计法与正交矩阵分解模型(PMF)分析了研究区浅层地下水中金属元素的主要来源,并在源解析的基础上运用健康风险评价模型对研究区健康风险现状进行评价。结果表明:①研究区地下水中超标率最高的金属元素为Mn,其含量最高达8.66mg/L,主要分布在滨海平原地区附近。②研究区浅层地下水中金属超标率较高的地区主要分布在滨海平原地区,其来源可以分为4种。第1种的特征因子为Fe,主要受到地质环境与工业活动的影响;第2种的特征因子为Mn,主要受到地质环境的影响;第3种的特征因子为Al,主要受到工业活动和矿山开采的影响;第4种的特征因子为Zn和Cr6+,主要受到工业活动的影响。③健康风险评价表明,研究区浅层地下水中金属元素引起受体人群身体健康的首要因素是致癌风险,首要暴露途径是经口摄入途径,首要致癌因子是Cr6+,首要非致癌因子是Mn。儿童的健康总风险高于成人,两种受体在空间上具有较高的一致性,较高风险地区主要集中在市区。从研究区受体人群安全角度考虑,应对研究区浅层地下水中的Mn和Cr6+进行重点管控。

     

    Abstract: In recent years, human activities have affected the groundwater environment, posing potential risks to human health. To investigate the effects of metal elements in groundwater on human health, this paper selects the plain area of Tangshan City, Hebei Province as the study area. A total of sixty-four shallow groundwater samples were collected from the district.. Ten metal elements, such as Fe and Mn, were detected, and their concentration characteristics were analyzed. The main sources of metal elements in the shallow groundwater area were analyzed by combining the geostatistical method and Positive Matrix Factorization (PMF). Based on the source analysis, a health risk assessment model was applied to evaluate the health risk status of the study area. The results showed that: (1) The metal element with the highest exceedance rate in the groundwater of the study area was Mn, with a maximum content of 8.66 mg/L, primarily found near the coastal plain. (2) The areas with high metal exceedance rates in shallow groundwater are primarily located in the coastal plain, and their sources can be classified into four categories Type 1 is characterized by Fe, primarily influenced by geological environment and industrial activities. Type 2 is characterized by Mn, mainly influenced by the geological environment. Type 3 is characterized by Al, mainly influenced by industrial activities and mining. Type 4 is characterized by Zn and Cr6+, mainly influenced by industrial activities. ③The health risk evaluation indicated that the primary concern for metallic elements in shallow groundwater is carcinogenic risk for the receptor population.. The main exposure route is the oral ingestion, with Cr6+ as the primary carcinogen and Mn as the main non-carcinogen. The total health risk for children is higher than for adults, with high spatial concordance between the both receptors, and higher risk areas concentrated in urban regions. To ensure the safety of the receptor population in the study area, efforts should focus on controlling Mn and Cr6+ levels in shallow groundwater.

     

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