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磺胺甲恶唑和卡马西平在孔隙介质中的吸附行为与影响因素研究

Adsorption Behavior and Influencing Factors of Sulfamethoxazole and Carbamazepine on Porous Media

  • 摘要: 磺胺甲恶唑(SMX)和卡马西平(CBZ)作为水环境中被广泛检出的药用活性化合物,其进入水土环境给生态环境和人体健康带来潜在风险。为探究SMX和CBZ进入不同类型土壤后的吸附行为,本文研究了SMX和CBZ在粉土及细砂两种典型孔隙介质中的吸附动力学、等温吸附特征及溶液pH值、可溶性腐植酸(DHA)和土壤矿物组分三种因素的影响。结果表明:SMX和CBZ在孔隙介质上的吸附均符合Lagergren准二级动力学模型和Langmuir等温吸附模型,具有快速吸附、缓慢平衡的特点,属于单分子层化学吸附。孔隙介质对SMX的吸附属于自发的放热反应,而对CBZ的吸附则是吸热反应。在实验条件下,粒径小、有机质含量高和比表面积较大的粉土对SMX和CBZ的最大吸附量分别是细砂的3.0倍和2.3倍。SMX的吸附主要受矿物表面静电引力和有机质分配作用影响,而CBZ更多受分配作用控制。随溶液pH值升高(pH=5.0~9.0),孔隙介质对主要以阴离子态存在的SMX的吸附量明显下降,而对分子态CBZ的吸附量变化不明显。溶液中DHA(8~50mg/L)的共存对孔隙介质吸附SMX和CBZ具有竞争抑制作用。孔隙介质中蒙脱石和铁氧化物的含量越高,其对SMX和CBZ的吸附能力越强。

     

    Abstract: This study results show that the adsorption processes of SMX and CBZ by pore media follow Lagergren model and Langmuir model. The adsorption process can be characterized by rapid adsorption and slow equilibrium and it is a monomolecular layer chemical adsorption. The adsorption of SMX is a spontaneous exothermic process, while the adsorption of CBZ is an endothermic process. Under the experimental conditions, the maximum adsorption capacity of SMX and CBZ of silt with small particle size, high organic matter content and large specific surface area is 3.0 times and 2.3 times of that of fine sand, respectively. The adsorption of SMX is mainly affected by the electrostatic attraction of mineral surface and the distribution of organic matter, while CBZ is more controlled by the distribution. The adsorption capacity of SMX in silt that existed mainly in anionic form increases with the increase of pH value (5.0~9.0), while the adsorption capacity of CBZ in molecular form does not change significantly with the change of pH. The coexistence of dissolved humic acid (8~50mg/L) inhibits the adsorption of SMX and CBZ. The adsorption capacity of SMX and CBZ increases with the increase of organic matter and iron oxide content in porous media. The BRIEF REPORT is available for this paper at http://www.ykcs.ac.cn/en/article/doi/10.15898/j.ykcs.202407110154.

     

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