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辽阳—丹东地区土壤重金属分布特征与源解析

Distribution Characteristics and Source Analysis of Soil Heavy Metals in the Liaoyang—Dandong Region

  • 摘要: 辽阳—丹东地区是辽宁省重要粮食与经济作物生产区,以往土壤重金属研究主要集中在200cm以浅,掌握土壤0~500cm重金属分布特征及来源,对监测黑土地质量及研究土壤重金属迁移转化意义重大。本文采集了1381件土壤表层(0~20cm)、160件土壤中层(150~250cm)和75件土壤深层(250~500cm)样品,对其中8种重金属元素和Sc等元素含量进行了测定,探讨研究区土壤重金属在不同层分布规律并解析来源。调查结果显示:土壤表层、中层和深层As、Cd、Cr、Hg、Co、Pb、Sc、Zn和Cu平均含量均未超过污染风险筛选值;通过多元统计,Cd和Hg表层富集明显,Pb和Zn表现一定富集趋势,Cd、Hg和Pb在表层分布不均匀;通过空间分析方法和地累积指数,研究区土壤表层中Cd、Hg、Pb和Zn整体表现为轻微污染,中度污染点零星分布在人员集中和采矿活跃区域;土壤中层Pb元素轻微污染,深层元素均未污染;利用Pearson相关性分析、主成分分析(PCA)和人为贡献率(ACR)揭示Pb、As、Co、Cu、Cr、Sc和Zn主要受自然背景的影响,Pb和Zn局部轻微受人为因素的影响,Cd和Hg则受人为活动的影响显著。研究区需要加强对Hg、Cd、Pb和Zn元素在不同地块富集趋势的监测,中层深度需要关注Pb的富集,同时开展区内不同流域土壤的Cd和Hg在不同层位的迁移转化研究。

     

    Abstract: The Liaoyang—Dandong region is an important grain and cash crop production area in Liaoning Province. It is of great significance for monitoring the quality of black soil and studying the migration and transformation of heavy metals in soil to understand the distribution characteristics and sources of heavy metals in soil from 0 to 500cm. Soil samples were collected from different layers, and the contents of 8 heavy metal elements and Sc elements were determined. The average contents did not exceed the pollution risk screening value, Cd and Hg were obviously enriched in the surface soil, and Pb and Zn showed a certain enrichment trend. Cd, Hg, Pb and Zn in the surface soil were slightly polluted, the middle layer of soil was slightly polluted by Pb, and the deep layer of soil was not polluted. Pb, As, Co, Cu, Cr, Sc and Zn were affected mainly by natural background, Pb and Zn were affected slightly by local human factors, and Cd and Hg were affected significantly by human activities. In the future, it will be necessary to strengthen the monitoring of the enrichment trend of Hg, Cd, Pb and Zn elements in different plots. The BRIEF REPORT is available for this paper at http://www.ykcs.ac.cn/en/article/doi/10.15898/j.ykcs.202404070080.

     

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