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海南琼中岩-土体系重金属迁移特征及表土环境质量评价

Migration Characteristics and Environmental Quality Assessment of Heavy Metal Elements in the Rock-Soil System in Qiongzhong, Hainan Island

  • 摘要: 地球关键带和土壤重金属污染是当今研究的前沿与热点,岩-土体系是地球关键带的重要组成部分。目前海南岛针对不同成壤母质岩-土体系的详细研究较少,并且重金属亟需基于新标准进行评价。为了查清岩-土体系中重金属元素迁移特征及污染状况,本文以海南岛琼中3个土壤垂向剖面及7115件表层土壤样品为研究对象,采用电感耦合等离子体质谱/发射光谱法(ICP-MS/OES)和原子荧光光谱法(AFS)等分析方法,测定岩石和土壤中Cu、Pb、Zn、Cr、Ni、Cd、As和Hg共8种重金属元素含量,利用土壤环境质量农用地土壤污染风险管控标准、内梅罗指数法和潜在生态危害指数法定量评价了表层土壤样品重金属污染状况及生态风险。结果表明,①海南岛琼中二长花岗岩岩-土体系中,不同重金属元素表现出明显的分异特征,Cu、Pb、Zn、Cr、Ni、Cd元素以亏损为主,As元素以富集为主,Hg元素则表现出不同的富集或亏损特征,As、Hg元素尤其富集在表层。②琼中绝大多数表层土壤中重金属元素含量低于土壤环境质量农用地土壤污染风险筛选值,土壤污染风险低。③以琼中和海南岛背景值为评价标准时,应关注Cr、Ni和As污染以及Hg、As和Cd的生态危害。以土壤环境质量为评价标准时,研究区表层土壤的环境质量总体清洁,生态风险较弱。

     

    Abstract: The rock-soil system is an important component of the Earth’s critical zone, but there are few detailed studies on different soil systems in Hainan Island. To clarify migration characteristics and environmental quality, three typical adamellite soil profiles and 7115 topsoil samples were collected from Qiongzhong, Hainan Island. The heavy metals Cu, Pb, Zn, Cr, Ni, Cd, As and Hg in rocks and soils were determined by ICP-MS/OES or AFS. Comprehensive evaluation shows that although heavy metal elements in the rock-soil system of the Qiongzhong research area exhibit diverse migration patterns and enrichment or deficiency characteristics, the overall environmental quality of the topsoil is relatively clean, with weak ecological risks. Different evaluation criteria and methods will lead to different evaluation results. It is suggested that a variety of evaluation methods and standards are adopted to carry out comprehensive evaluation in order to obtain more real, objective, and accurate evaluation results. The BRIEF REPORT is available for this paper at http://www.ykcs.ac.cn/en/article/doi/10.15898/j.ykcs.202308040122.

     

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