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X射线衍射和TIMA研究陕南镇巴地区富锂黏土岩的矿物组成及锂的赋存状态

Mineralogical Composition and Occurrence State of Lithium in Lithium-Enriched Claystone in the Zhenba Area, Southern Shaanxi, by X-Ray Diffraction and TIMA Analysis

  • 摘要: 黏土岩型锂矿作为可利用锂资源的重要组成部分,由于其分布广、储量大而备受关注。陕西镇巴地区晚二叠世吴家坪组新发现黏土岩型锂矿(资源),Li2O最高含量可达0.39%,达到了黏土锂矿的工业指标(0.2%),具有一定的开发利用价值。为了查明陕南镇巴地区富锂黏土岩中黏土矿物种类、含量及富锂黏土岩中锂的赋存状态,本文选取陕西镇巴地区富锂黏土岩,通过偏光显微镜鉴定初步查明黏土岩的矿物组成,利用X射线衍射(XRD)、全自动综合矿物分析系统(TIMA)分析技术定量查明富锂黏土岩中黏土矿物及主要元素含量。结果表明:该黏土岩主要由高岭石、铝绿泥石、伊利石、锂绿泥石等黏土矿物以及赤铁矿组成,含少量绿泥石、金红石等矿物。TIMA分析表明样品中锂绿泥石最高含量为8.94%,对应锂含量为0.12%(Li2O含量为0.26%),略低于该样品全岩Li2O含量(0.31%)。锂绿泥石呈丝缕状,不规则粒状,嵌布于一水软铝石、伊利石、铝绿泥石之间。综合研究认为镇巴地区富锂黏土岩中锂主要赋存于锂绿泥石中,其他矿物的锂含量很低。锂绿泥石、伊利石、高岭石等层状结构硅酸岩矿物具有很好的吸附性,锂以Li+形式吸附于黏土矿物中。

     

    Abstract: The newly discovered clay-type lithium ore (resources) in the upper Permian Wujiaping Formation in the Zhenba area of Shanxi Province has a maximum Li2O content of 0.39%, which reaches the industrial index of clay lithium ore (0.2%), and has certain development and utilization values. To determine the mineral’s composition of lithium-enriched claystone and the occurrence state of lithium, a microscope was used to preliminarily observe the mineral composition, X-ray diffraction (XRD) and TIMA (TESCAN Integrated Mineral Analyzer) were used to analyze clay minerals and the main elemental content. The lithium-enriched claystone in the Zhenba area is mainly composed of kaolinite, sudoite, illite, cookeite and hematite, containing a small amount of chlorite, rutile and other minerals. TIMA analysis shows that the highest content of cookeite is 8.94%, and the highest Li content is 0.12% (Li2O content is 0.26%), which is slightly lower than the whole rock Li2O value (0.31%). The cookeite is silky and irregularly granular, and is dispersed between boehmite, illite and sudoite. The results show that lithium in claystone occurs mainly in cookeite, and other clay minerals have low lithium content.

     

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