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粉色水晶内针状包裹体的成分与分布特征研究

Study on the Component and Distribution Characteristics of Needle-like Inclusions in Rose Quartz

  • 摘要: 粉色水晶内部的针状包裹体常被认为是三组呈三方对称的金红石或蓝线石,至今未有定论。本文选取含有针状包裹体的4颗星光粉晶,利用宝石学显微镜、激光拉曼光谱仪及紫外可见分光光度计对样品进行观察与测试,以确定包裹体的分布特征及矿物种类。无损拉曼测试发现包裹体的特征振动峰949 cm-1、999 cm-1与蓝线石标准峰相匹配,可确定针状包裹体为蓝线石或与其极为相近的矿物。放大检查发现,包裹体直径约0.5 μm,长度可达毫米级,近定向分布,整体上呈汇聚状,在某些位置可粗略分为三组,同组针状包裹体近似平行分布。造成六射星光的三组蓝线石立体相交,未观察到明显的三方对称关系,与水晶的结晶习性无直接关系,故认为蓝线石为先成包裹体,在水晶的生长过程中被捕获。紫外可见分光光谱仅显示粉色蓝线石的特征吸收,表明大量的粉色蓝线石包裹体对粉色水晶的粉色有一定贡献。

     

    Abstract:
    BACKGROUND The needle-like inclusions in rose quartz are considered to be rutile or dumortierite, and their orientation is related to the c-axis. However, there is no consensus on this statement.
    OBJECTIVES To find out the distribution characteristics and component of needle-like inclusions in rose quartz using multiple methods.
    METHODS Four starlight powder crystals containing acicular inclusions were selected, observed and tested using gemological Microscopes, Laser Raman Spectroscopy, and Ultraviolet-visible Absorption Spectroscopy.
    RESULTS The Raman experiments show that the characteristic vibration peaks 949 cm-1 and 999 cm-1 of needles match those of dumortierite and the needle-like inclusions are dumortierite or minerals similar to dumortierite. Magnification examination reveals that the inclusions are approximately 0.5 μm in diameter, with a length of up to millimeters, a near-directional distribution, and a convergent shape as a whole. They can be roughly divided into three groups at certain positions. The needle-like inclusions in the same group are distributed approximately parallel. The three blue-ray lines of six-pointed starlights intersected three-dimensionally, and no obvious three-dimensional symmetry was observed. It was not directly related to the crystallization habit of crystals.
    CONCLUSIONS It is believed that blue-ray stones form inclusions first and are captured during the growth of crystals. The UV-visible Spectroscopic Spectrum only absorbs the pink dumortierite, indicating that a large number of pink dumortierite inclusions contribute to the pinkness of the pink crystal.

     

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